2024
485) F. Schäfer, L. Lückemeier, F. Glorius,
Improving reproducibility through condition-based, sensitivity assessments: application, advancement, and prospect,
Chem. Sci. 2024, 15, 14548-14555. DOI
484) F.-P. Wu, M. Lenz, A. Suresh,§ A. R. Gogoi,§ J. L. Tyler, C. G. Daniliuc, O. Gutierrez,* F. Glorius*,
Nitrogen-to-functionalized carbon atom transmutation of pyridine,
Chem. Sci. 2024, 15, 15205-15211. DOI
§ These authors contributed equally.
483) F.-P. Wu, J. L. Tyler, C. G. Daniliuc, F. Glorius,
Atomic Carbon Equivalent: Design and Application to Diversity- Generating Skeletal Editing from Indoles to 3‑Functionalized Quinolines,
ACS Catal. 2024, 14, 13343-13351. DOI
482) S. P. Schmid,§ L. Schlosser,§ F. Glorius,* K. Jorner,*
Catalysing (organo-) catalysis: Trends in the application of machine learning to enantioselective organocatalysis,
Beilstein J. Org. Chem. 2024, 20, 2280-2304. DOI
§ These authors contributed equally.
481) J. Gemen,§ B. Stövesand,§ F. Glorius,* B. J. Ravoo,*
Surface Tension Manipulation with Visible Light through Sensitized Disequilibration of Photoswitchable Amphiphiles,
Angew. Chem. Int. Ed. 2024, 63, e202413209; Angew. Chem. 2024, 136, e202413209. DOI
§ These authors contributed equally.
480) C. Schultz,§ T. Wegner,§ C. Heusel, Tim Gallagher, Y. Zheng, M. Werner, S. V. Wegner, T. Meyer-Zedler, O. Werz, M. Schmitt, J. Popp,* F. Glorius,*
Alkyne-tagged imidazolium-based membrane cholesterol analogs for Raman imaging applications,
Chem. Sci. 2024, 15, 14323-14335. DOI
§ These authors contributed equally.
479) F. Zhang, H. Sekhar Sasmal,§ D. Rana,§ F. Glorius,
Switchable and Chemoselective Arene Hydrogenation for Efficient Late Stage Applications,
J. Am. Chem. Soc. 2024, 146, 18682-18688. DOI
§ These authors contributed equally.
478) J. L. Tyler,§ F. Schäfer,§ H. Shao, C. Stein, A. Wong, C. G. Daniliuc, K. N. Houk*, F. Glorius,*
Bicyclo[1.1.0]butyl Radical Cations: Synthesis and Application to [2π + 2σ] Cycloaddition Reactions,
J. Am. Chem. Soc. 2024, 146, 16237-16247. DOI
§ These authors contributed equally.
477) F. Landwehr,§ M. Das,§ S. Tosoni,§,* J. J. Navarro, A. Das, M. Koy, M. Heyde,* G. Pacchioni, F. Glorius,* B. Roldan Cuenya,
N-Heterocyclic Olefins on a Metallic Surface – Adsorption, Orientation and Electronic Influence,
Adv. Mater. Interfaces 2024, 11, 2400378. DOI
§ These authors contributed equally.
476) L. Schlosser, D. Rana, P. Pflüger, F. Katzenburg, F. Glorius,
EnTdecker – A machine learning-based platform for guiding substrate discovery in energy transfer catalysis,
J. Am. Chem. Soc. 2024, 146, 13266-13275. DOI
475) D.-H. Liu,§ P. M. Pflüger,§ A. Outlaw,§ L. Lückemeier, F. Zhang, C. Regan, H. Rashidi Nodeh, T. Cernak,* J. Ma,* F. Glorius,*
Late-Stage Saturation of Drug Molecules,
J. Am. Chem. Soc. 2024, 146, 11866-11875. DOI
§ These authors contributed equally.
Highlighted by Synfacts 2024, 20, 0752. DOIHighlighted by Shanghai Jiao Tong University (SJTU; chinese);
Highlighted in Chemistry World (“'Late-state saturation' could boost drug discovery”).
474) F. Strieth-Kalthoff,§ S. Szymkuc,§ K. Molga,§ A. Aspuru-Guzik, F. Glorius,* B. A. Grzybowski,*
Artificial Intelligence for Retrosynthetic Planning Needs Both Data and Expert Knowledge,
J. Am. Chem. Soc. 2024, 146, 11005-11017. DOI
§ These authors contributed equally.Highlighted by ChemistryViews;
Highlighted by Derek Lowe (IN THE PIPELINE);
highlighted by press release of Chemistry World (“Are we rushing ahead with AI in the lab?”).
473) D. Rana, P. M. Pflüger, N. P. Hölter, G. Tan, F. Glorius,
Standardizing Substrate Selection: A Strategy toward Unbiased Evaluation of Reaction Generality,
ACS Cent. Sci. 2024, 10, 899-906. DOIHighlighted by press release of Uni MS (english),
highlighted by press release of Uni MS (german);
highlighted by press releases of Chemeurope.com, ScienceDaily, Eurekalert, Chemie.de (german), Analytik.de (german), Analytik.news (german), Chemiextra (german), Chemeurope (french), Quimica.es (spanish).
Highlighted in C&E News (“Free tool uses machine learning to pick better molecules for testing new reactions”).
472) M. L. Schrader,§ F. R. Schäfer,§ F. Schäfers,§ F. Glorius,
Bridging the information gap in organic chemical reactions,
Nat. Chem. 2024, 16, 491-498. DOI
§ These authors contributed equally.
SharedIt link
471) R. Laskar,§ S. Dutta,§ J. C. Spies, P. Mukherjee, A. Renteria-Gomez, R. E. Thielemann, C. G. Daniliuc, O. Gutierrez,* F. Glorius,*
γ-Amino Alcohols via Energy Transfer Enabled Brook Rearrangement,
J. Am. Chem. Soc. 2024, 146, 10899-10907. DOI
§ These authors contributed equally.
470) Y. Liang, R. Nematswerani, C. G. Daniliuc, F. Glorius,
Silver-Enabled Cycloaddition of Bicyclobutanes with Isocyanides for the Synthesis of Polysubstituted 3-Azabicyclo[3.1.1]heptanes,
Angew. Chem. Int. Ed. 2024, 63, e202402730; Angew. Chem. 2024, 136, e202402730. DOIDedicated to Professor Helmut Schwarz on the occasion of his 80th birthday
469) P. M. Pflüger,§ M. Kühnemund,§ F. Katzenburg,§ H. Kuchen, F. Glorius,
An evolutionary algorithm for interpretable molecular representations,
Chem 2024, 10, 1391-1405. DOI
§ These authors contributed equally; selected for cover image.Highlighted by press release of Uni MS (english),
highlighted by press release of Uni MS (german);
highlighted by press releases of Computational Chemistry Highlights, chemeurope.com, idw-online.de, Research-in-Germany.org, Phys.org, msn.com, Chemie.de (german), Analytik.de (german), Quimica.es (spanish).
468) S. Dutta, Y.-L. Lu,§ J. E. Erchinger,§ H. Shao, E. Studer, F. Schäfer, H. Wang, D. Rana, C. G. Daniliuc, K. N. Houk,* F. Glorius,*
Double Strain-Release [2π+2σ]-Photocycloaddition,
J. Am. Chem. Soc. 2024, 146, 5232-5241. DOI
§ These authors contributed equally.
467) J. Ren,*§ M. Das,§ H. Osthues, M. Nyenhuis, B. Schulze Lammers, E. Kolodzeiski, H. Mönig, S. Amirjalayer,* H. Fuchs,* N. L. Doltsinis,* F. Glorius,*
The electron-rich and nucleophilic N-heterocyclic imines on metal surfaces: binding modes and interfacial charge transfer,
J. Am. Chem. Soc. 2024, 146, 7288-7294. DOI
§ These authors contributed equally.
466) L. Lückemeier,§ T. De Vos,§ L. Schlichter, C. Gutheil, C. G. Daniliuc, F. Glorius,
Chemoselective Heterogeneous Hydrogenation of Sulphur Containing Quinolines Under Mild Conditions,
J. Am. Chem. Soc. 2024, 146, 5864-5871. DOI
§ These authors contributed equally.Highlighted by Synfacts 2024, 20, 0622. DOI
465) C. Gutheil, G. Ross, S. Amirjalayer, B. Mo, A. H. Schäfer, N. L. Doltsinis, B. Braunschweig,* F. Glorius,*
Tailored Monolayers of N-Heterocyclic Carbenes by Kinetic Control,
ACS Nano 2024, 18, 3043-3052. DOI
464) S. Dutta,§ D. Lee,§ K. Ozols,§ C. Daniliuc, R. Shintani, F. Glorius,
Photoredox-Enabled Dearomative [2π+2σ] Cycloaddition of Phenols,
J. Am. Chem. Soc. 2024, 146, 2789-2797. DOI
§ These authors contributed equally.Highlighted in Synfacts 2024, 20, 0409. DOI
463) F.-P. Wu, C. C. Chintawar, R. Lalisse, P. Mukherjee, S. Dutta, J. Tyler, C. G. Daniliuc, O. Gutierrez,* F. Glorius,*
Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion,
Nat. Catal. 2024, 7, 242-251. DOIHighlighted by press release of Uni MS (english),
highlighted by press release of Uni MS (german);
highlighted by press releases of Advanced_Science_News,
Phys.org, Industr.com, Chemeurope.com, Vervetimes.com, Sciencedaily.com, Myscience.org, TheDailyScience, Bnn.breaking.com,
CHEManager (german), Innovations-Report.de (german), Chemie.de (german), Laborpraxis.vogel.de (german), Analytik.news (german), Process.vogel.de (german), Chemeurope.com (french), Quimica.es (spanish).
462) S. Dutta, J. E. Erchinger, F. Strieth-Kalthoff, R. Kleinmans, F. Glorius,
Energy transfer photocatalysis: exciting modes of reactivity,
Chem. Soc. Rev. 2024, 53, 1068-1089. DOI
2023
461) J. Goretzko, I. Pauels, N. Heitzig, K. Thomas, M. Kardell, J. Naß, E. Kleinhans Krogsaeter, S. Schloer, B. Spix, A. L. L. Matos, C. Leser, T. Wegner, F. Glorius, F. Bracher, V. Gerke, J. Rossaint, C. Grimm, U. Rescher,*
P-selectin-dependent leukocyte adhesion is governed by endolysosomal two-pore channel 2,
Cell Rep. 2023, 42, 113501. DOI
460) M. Das,§ C. Hogan,§ R. Zielinski, M. Kubicki, M. Koy, C. Kosbab, S. Brozzesi, A. Das, M. T. Nehring, V. Balfanz, J. Brühne, M. Dähne, M. Franz,* N. Esser,* F. Glorius,*
N-Heterocyclic Olefins on a Silicon Surface,
Angew. Chem. Int. Ed. 2023, 62, e202314663; Angew. Chem. 2023, 135, e202314663. DOI
§ These authors contributed equally.
459) H. Wang,§ J. E. Erchinger,§ M. Lenz,§ S. Dutta, C. G. Daniliuc, F. Glorius,
syn-Selective Difunctionalization of Bicyclobutanes Enabled by Photoredox-Mediated C–S σ-Bond Scission,
J. Am. Chem. Soc. 2023, 145, 23771-23780. DOI
§ These authors contributed equallyHighlighted in Synfacts 2024, 20, 0078. DOI
458) T. Wegner,§ A. Dombovski,§ K. Gesing, A. Köhrer, M. Elinkmann, U. Karst, F. Glorius* J. Jose,*
Combining lipid-mimicking-enabled transition metal and enzyme-mediated catalysis at the cell surface of E. coli,
Chem. Sci. 2023, 14, 11896-11906. DOI
§ These authors contributed equally
457) F. Paulus, C. Stein, C. Heusel, T. J. Stoffels, C. G. Daniliuc, F. Glorius,
Three-Component Photochemical 1,2,5-Trifunctionalizations of Alkenes towards Densely Functionalized Lynchpins,
J. Am. Chem. Soc. 2023, 145, 23814-23823. DOI
456) F. Buß, M. Das, D. Janssen-Müller, A. Sietmann, A. Das, L. F. B. Wilm, M. Freitag, M. Seidl, F. Glorius* F. Dielmann*,
Photoswitchable Electron-rich Phosphines: Using Light to Modulate the Electron-Donating Ability of Phosphines,
Chem. Commun. 2023, 59, 12019-12022. DOIDedicated to Holger Braunschweig on the occasion of his 60th birthday.
455) P. Bellotti,* F. Glorius,*
Strain-Release Photocatalysis,
J. Am. Chem. Soc. 2023, 145, 20716-20732. DOI
454) J. Ren, M. Koy, H. Osthues, B. Schulze Lammers, C. Gutheil, M. Nyenhuis, Q. Zheng, Y. Xiao, L. Huang, A. Nalop, Q. Dai, H.-J. Gao,* H. Mönig,* N. L. Doltsinis,* H. Fuchs,* F. Glorius,*
On-surface synthesis of ballbot-type N-heterocyclic carbene polymers,
Nat. Chem. 2023, 15, 1737-1744. DOIHighlighted by press release of Uni MS (english),
highlighted by press release of Uni MS (deutsch);
highlighted by press releases of Research-in-Germany, EurekAlert, Behind the paper (by Prof. Jindong Ren), Phys.org, myScience.de, chemEurope.com, Headtopics.com, Chemie.de (german), Laborpraxis.vogel.de (german), Jot-oberflaeche.de (german), Pro-physik.de (german), Chinese Academy of Science (chinese), Quimica.es (spanish), Chemeurope.com/fr (french).
453) L. Quach, E. Adhitama,§ V. Göldner,§ A. Das, F. Demelash, M. Winter,* U. Karst,* T. Placke,* F. Glorius,*
Molecular Design of Film-Forming Additives for Lithium-Ion Batteries – Impact of Molecular Substrate Parameters on Cell Performance,
ACS Appl. Energy Mater. 2023, 6, 9837-9850. DOI
§ These authors contributed equally
452) M. Das, M. Kohlstädt,* M. Enders, S. Burger, H. S. Sasmal, B. Zimmermann, A. Schäfer, B. J. Tyler, H. F. Arlinghaus, I. Krossing, U. Würfel, F. Glorius,*
Surface Modification of ITO with N-Heterocyclic Carbene Precursors Results in Electron Selective Contacts in Organic Photovoltaic Devices,
Chem. Eur. J. 2023, 29, e202301482. DOI
451) V. Göldner, L. Quach, E. Adhitama, A. Behrens, L. Junk, M. Winter, T. Placke, F. Glorius, U. Karst,*
Laser desorption/ionization-mass spectrometry for the analysis of interphases in lithium ion batteries,
iScience 2023, 26, 107517. DOI
450) F. Bosse, C. Gutheil, D. T. Nguyen, M. Freitag, M. Das, B. J. Tyler, T. Adolphs, A. H. Schäfer, H. F. Arlinghaus, F. Glorius,* B. J. Ravoo,*
Selective Removal of Gold: N-Heterocyclic Carbenes as Positive Etch Resists on Planar Gold Surfaces,
ACS Appl. Mater. Interfaces 2023, 15, 36831-36838. DOI
449) H. Wang, H. Shao,§ A. Das,§ S. Dutta, H. T. Chan, C. Daniliuc, K. N. Houk,* F. Glorius,*
Dearomative ring expansion of thiophenes by bicyclobutane insertion,
Science 2023, 381, 75-81. DOI
§ These authors contributed equally
Free-access electronic reprintHighlighted by press release of WWU (german),
highlighted by press release of WWU (english),
highlighted by press releases of Chemistry World, ChemEurope.com, MyScience.org, Technologynetworks.com, Enenews.co.kr, TheDailyScience.com, Newsbeezer.com, Phys.org, Chemie.de (german), Idw-online.de (german), Analytik.News (german), Laborpraxis.Vogel.de (german), Industr.com (german), Quimica.es (spanish), ChemEurope.com (french).
448) L. Lückemeier,§ M. Pierau,§ F. Glorius,
Asymmetric arene hydrogenation: towards sustainability and application,
Chem. Soc. Rev. 2023, 52, 4996-5012. DOI
§ These authors contributed equallyHighlighted as Highlights from the literature by Org. Process Res. Dev. 2023, 27, 1535-1545. DOI
447) F. Zhang, H. S. Sasmal, C. G. Daniliuc, F. Glorius,
Ru-NHC-Catalyzed Asymmetric, Complete Hydrogenation of Indoles and Benzofurans: One Catalyst with Dual Function,
J. Am. Chem. Soc. 2023, 145, 15695-15701. DOIHighlighted by ACS as editor’s choice.
Highlighted as Highlights from the literature by Org. Process Res. Dev. 2023, 27, 1827-1840. DOI
446) Y. Liang, F. Paulus, C. G. Daniliuc, F. Glorius,
Catalytic Formal [2π+2σ] Cycloaddition of Aldehydes with Bicyclobutanes: Expedient Access to Polysubstituted 2-Oxabicyclo[2.1.1]hexanes,
Angew. Chem. Int. Ed. 2023, 62, e202305043; Angew. Chem. 2023, 135, e202305043. DOIDedicated to Professor Keiji Maruoka on the occasion of his 70th birthday.
445) J. L. Tyler,§ F. Katzenburg,§ F. Glorius,
A focus on sustainable method development for greener synthesis,
Chem. Sci. 2023, 14, 7408-7410. DOI
§ These authors contributed equally
444) H. Wang, Z. Liu, A. Das, P. Bellotti, S. Megow, F. Temps,* X. Qi,* F. Glorius,*
Radical thioesterification via nickel-catalyzed sensitized electron transfer,
Nature Synth. 2023, 2, 1116-1126. DOI
443) T. Wegner,§ A. L. L. Matos,§ K. Porte,§ K. Mehring,§ M. Pierau,§ H. Horstmeier, V. Gerke,* F. Glorius,*
A bifunctional imidazolium-based cholesterol analog for the tracking of cellular cholesterol distributions and cholesterol–protein interactions,
Org. Biomol. Chem. 2023, 21, 4817-4822. DOI
§ These authors contributed equally
442) Y. Lee,§ X. Liu,§ Y. Tong,§ J. L. Childs-Disney,§ B. M. Suresh, R. I. Benhamou, C. Yang, W. Li, M. G. Costales, H. S. Haniff, S. Sievers, D. Abegg, T. Wegner, T. O. Paulisch, E. Lekah, M. Grefe, G. Crynenf, M. Van Meter, J. L. Cleveland, A. Adibekian, F. Glorius,*, H. Waldmann,* M. D. Disney*,
Programming inactive RNA-binding small molecules into bioactive degraders,
Nature 2023, 618, 169-179. DOI
§ These authors contributed equallyHighlighted by press release of WWU (german),
highlighted by press release of WWU (english),
highlighted by press releases of MPG.de, Myscience.de, University of Florida,
Genengnews.com, Technologynetworks.com, Technology.org, TU Dortmund, ScienceMag.com, MedicalXpress.com, Miragenews.com, Newatlas.com, Bioengineer.org, Ruhrbarone (german), Westfalenspiegel (german), TU Dortmund (german), Agenciasinc.es (spanish), Madrimasd.org (spanish), Theobjective.com, Infosalus.com (spanish).
441) R. Kleinmans,§ S. Dutta,§ K. Ozols, H. Shao, F. Schäfer, R. E. Thielemann, H. T. Chan, C. G. Daniliuc, K. N. Houk,* F. Glorius,*
ortho-Selective Dearomative [2π + 2σ]-Photocycloadditions of Bicyclic Aza-Arenes,
J. Am. Chem. Soc. 2023, 145, 12324-12332.DOI
§ These authors contributed equallyHighlighted by Synfacts 2023, 19(08), 0775. DOI
440) R. Zielinski, M. Das, C. Kosbab, M. T. Nehring, M. Dähne, N. Esser,* M. Franz*, F. Glorius,*
Influence of the defect density on the ordering of an NHC monolayer on a silicon surface,
J. Mater. Chem. C 2023, 11, 7377-7382.DOI
439) Y. Zheng,§ T. Wegner,§ D. Di Iorio, M. Pierau, F. Glorius,* S. V. Wegner,*
NTA-Cholesterol Analogue for the Nongenetic Liquid-Ordered Phase-Specific Functionalization of Lipid Membranes with Proteins,
ACS Chem. Biol. 2023, 18, 1435-1443. DOI
§ These authors contributed equally
438) G. Tan,§ F. Paulus,§ A. Petti, M.-A. Wiethoff, A. Lauer, C. Daniliuc, F. Glorius,
Metal-free photosensitized radical relay 1,4-carboimination across two distinct olefins,
Chem. Sci. 2023, 14, 2447-2454.DOI
§ These authors contributed equally
437) A. Kaithal, H. Sekhar Sasmal, S. Dutta, F. Schäfer, L. Schlichter, F. Glorius,
cis-Selective Hydrogenation of Aryl Germanes: A Direct Approach to Access Saturated Carbo- and Heterocyclic Germanes,
J. Am. Chem. Soc. 2023, 145, 4109-4118.DOI
436) M. Dellin, I. Rohrbeck, P. Asrani, J. A. Schreiber, N. Ritter, F. Glorius, B. Wünsch, T. Budde, L. Temme, T. Strünker, B. Stallmeyer, F. Tüttelmann, S. G. Meuth, M. Spehr, J. Matschke, A. Steinbicker, C. Gatsogiannis, R. Stoll, N. Strutz-Seebohm, G. Seebohm,
The second PI(3,5)P2 binding site in the S0 helix of KCNQ1 stabilizes PIP2-at the primary PI1 site with potential consequences on intermediate-to-open state transition,
Biol. Chem. 2023, 404, 241-254.DOI
435) P. Bellotti,§ H.-M. Huang*,§ T. Faber, F. Glorius*,
Photocatalytic Late-Stage C–H Functionalization,
Chem. Rev. 2023, 123, 4237-4352.DOI
§ These authors contributed equally
434) J. E. Erchinger, R. Hoogesteger,§ R. Laskar,§ S. Dutta, C. Hümpel, D. Rana, C. G. Daniliuc, F. Glorius,
EnT-Mediated N–S Bond Homolysis of a Bifunctional Reagent Leading to Aliphatic Sulfonyl Fluorides,
J. Am. Chem. Soc. 2023, 145, 2364-2374. DOI
§ These authors contributed equally
433) G. Tan, F. Glorius,
Stereochemical Editing,
Angew. Chem. Int. Ed. 2023, 62 (11), e202217840; Angew. Chem. 2023, 135 (11), e202217840. DOI
432) S. Ikemoto, S. Muratsugu,* T. Koitaya, Y. Tsuj, M. Das, K. Yoshizawa, F. Glorius, M. Tada,*
Coordination-Induced Trigger for Activity: N‑Heterocyclic Carbene-Decorated Ceria Catalysts Incorporating Cr and Rh with Activity Induction by Surface Adsorption Site Control,
J. Am. Chem. Soc. 2023, 145, 1497-1504. DOI
2022
431) G. Tan, M. Das, R. Kleinmans, F. Katzenburg, C. Daniliuc, F. Glorius,
Energy Transfer-Enabled Unsymmetrical Diamination Using Bifunctional Nitrogen-Radical Precursors,
Nat. Catal. 2022, 5, 1120-1130. DOIHighlighted by press release of WWU Münster (english),
highlighted by press release of WWU Münster (german),
highlighted by press releases of Phys.org, Idw-online.de,
VerveTimes.com, radioQ.de (german), Crumpe.com (french), Innovations-Report.com, ChemEurope.com, ChemEurope.com (french), Citizenside.fr (french), Quimica.es (spanish), Process.Vogel.de (german), Labmanager.com, Scienmag.com.
430) G. Tan, F. Paulus, Á. Rentería-Gómez,§ R. F. Lalisse,§ C. G. Daniliuc, O. Gutierrez*, F. Glorius*,
Highly Selective Radical Relay 1,4-Oxyimination of Two Electronically Differentiated Olefins,
J. Am. Chem. Soc. 2022, 144, 21664-21673. DOI
§ These authors contributed equallyHighlighted in this VIDEO “Five Important Papers in Organic Synthesis (November 2022)”;
Highlighted in Synfacts 2023, 19, 0292, DOI;
Highlighted by press release of nanoer.net.
429) Y. Liang, R. Kleinmans, C. G. Daniliuc, F. Glorius,
Synthesis of Polysubstituted 2-Oxabicyclo[2.1.1]hexanes via Visible-Light-Induced Energy Transfer,
J. Am. Chem. Soc. 2022, 144, 20207-20213. DOI
Highlighted by press release of chemrss.com.
428) D. A. Evans , J. J. Beiger*, J. D. Burch, P. H. Fuller, F. Glorius, E. Kattnig, D. A. Thaisrivongs, W. C. Trenkle, J. M. Young, J. Zhang,
Total Synthesis of Aflastatin A,
J. Am. Chem. Soc. 2022, 144, 19953-19972. DOIDedicated to the memory of David A. Evans (1941−2022).
427) J. J. Navarro, M. Das, S. Tosoni*, F. Landwehr, M. Heyde*, G. Pacchioni, F. Glorius*, B. Roldan Cuenya,
Promoted Thermal Reduction of Copper Oxide Surfaces by N-Heterocyclic Carbenes,
J. Phys. Chem. C 2022, 126, 17528-17535. DOI
426) S. Dutta,§ J. E. Erchinger,§ F. Schäfers, A. Das, C. G Daniliuc, F. Glorius,
Chromium/Photoredox Dual-Catalyzed Synthesis of α-Benzylic Alcohols, Isochromanones, 1,2-Oxy Alcohols and 1,2-Thio Alcohols,
Angew. Chem. Int. Ed. 2022, 61 (49), e202212136; Angew. Chem. 2022, 134 (49), e202212136. DOI
§ These authors contributed equallyDedicated to Professor Alois Fürstner on the occasion of his 60th birthday.
425) F. Schäfers,§ S. Dutta,§ R. Kleinmans, C. Mück-Lichtenfeld, F. Glorius,
Asymmetric Addition of Allylsilanes to Aldehydes – A Cr/Photoredox Dual Catalytic Approach Complementing the Hosomi–Sakurai Reaction,
ACS Catal. 2022, 12, 12281-12290. DOI
§ These authors contributed equallyHighlighted by Org. Chem. Highlights
424) T. Wegner, R. Laskar, F. Glorius,
Lipid mimetics: A versatile toolbox for lipid biology and beyond,
Curr. Opin. Chem. Biol. 2022, 71, 102209. DOI
423) R. Guo, S. Adak, P. Bellotti, X. Gao, W. W. Smith, S. N. Le, J. Ma, K. N. Houk*, F. Glorius*, S. Chen*, M. K. Brown*,
Photochemical Dearomative Cycloadditions of Quinolines and Alkenes: Scope and Mechanism Studies,
J. Am. Chem. Soc. 2022, 144, 17680-17691. DOI
422) J. J. Navarro, M. Das, S. Tosoni*, F. Landwehr, J. P. Bruce, M. Heyde*, G. Pacchioni, F. Glorius*, B. Roldan Cuenya,
Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface,
J. Am. Chem. Soc. 2022, 144, 16267-16271. DOIHighlighted in ChemistryViews
421) T. Wegner,§ R. Elias,§ L. Roling, N. Raj, V. Gerke, M. Fridman*, F. Glorius*,
Cationic, steroid-based imidazolium amphiphiles show tunable backbone-dependent membrane selectivity in fungi,
ACS Infect. Dis.2022, 8, 1815-1822. DOI
§ These authors contributed equally
420) P. Bellotti,§ T. Rogge,§ F. Paulus,§ R. Laskar, N. Rendel, J. Ma, K. N. Houk*, F. Glorius*,
Visible-Light Photocatalyzed peri-(3 + 2) Cycloadditions of Quinolines,
J. Am. Chem. Soc. 2022, 144, 15662-15671. DOI
§ These authors contributed equally
419) R. J. Lewis,§ M. Koy,§ M. Macino, M. Das, J. H. Carter, D. J. Morgan, T. E. Davies, J. B. Ernst, S. J. Freakley, F. Glorius*, G. J. Hutchings*,
N-Heterocyclic Carbene Modified Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide,
J. Am. Chem. Soc. 2022, 144, 15431-15436. DOI
§ These authors contributed equallyThis paper is dedicated to Guy Bertrand on the occasion of his 70th birthday.
418) M. Korff, T. O. Paulisch, F. Glorius, N. L. Doltsinis, B. Wünsch*,
Photocatalytic Isomerization of (E)-Anethole to (Z)-Anethole,
Molecules 2022, 27, 5342. DOI
417) G. Tan, M. Das, H. Keum, P. Bellotti, C. Daniliuc, F. Glorius,
Photochemical single-step synthesis of β-amino acid derivatives from alkenes and (hetero)arenes,
Nature Chem. 2022, 14, 1174-1184. DOI
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highlighted by press releases of Phys.org, ScienceDaily.com, EurekAlert!, Idw-online.de, Idw-online.de (german), Innovations-report.de (german), Chemie.de (german), Labo.de (german), Analytik.news (german), Scinexx.de (german), Miragenews.com, Bioengineer.com, Newscontinue.com, Seniorngr.com, Newswise.com, Vervetimes.com, Mydroll.com, Flipboard.com, Technocharger.com, Newsliveflorida.com, Chemeurope.com, Quimica.es (spanish), Chemeurope.com (french), Citizenside.fr (french).
416) P. Bellotti,§ H.-M. Huang,§ T. Faber, R. Laskar, F. Glorius,
Catalytic Defluorinative Ketyl-Olefin Coupling by Halogen-Atom Transfer,
Chem. Sci. 2022, 13, 7855-7862. DOI
§ These authors contributed equally
415) T. Wagener, M. Pierau, A. Heusler, F. Glorius,
Synthesis of Saturated N-Heterocycles via a Catalytic Hydrogenation Cascade,
Adv. Synth. Catal. 2022, 364, 3366-3371. DOI
This manuscript is part of a special issue dedicated to Andreas Pfaltz. For the editorial, see:
https://onlinelibrary.wiley.com/doi/10.1002/adsc.20220097
414) H.-M. Huang,§* P. Bellotti,§ S. Kim, X. Zhang, F. Glorius,*
Catalytic multicomponent reaction involving a ketyl-type radical,
Nature Synth. 2022, 1, 464-474. DOI
Free SharedIt-Link
§ These authors contributed equallyHighlighted by press release of WWU Münster (german);
highlighted by press release of WWU Münster (english);
highlighted by press releases of idwOnline (german), Wissenschaftler.de (german), Prozess.Vogel.de (german), EurekAlert!, NewsKnowledia.com, myScience.de, Face-port.com, ChemEurope.com, AnalyticalScience.wiley.com, Nouvells-du-monde.com (french), Phys.org, Fr.postsus.com (french), Jaituss.com, Evanstips.com, Newsbeezer.com, Innovations-Report.de (german), Analytik.news (german).
Highlighted by Research Briefing by Nature Synthesis.
413) J. Ma,§ S. Chen,§ P. Bellotti,§ T. Wagener, C. Daniliuc, K. N. Houk,* F. Glorius,*
Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2+2] cycloaddition/rearrangement reactions of quinolines with alkenes,
Nature Catal. 2022, 5, 405-413. DOI
Free SharedIt-Link
§ These authors contributed equallyHighlighted by press release of WWU Münster (german);
highlighted by press release of WWU Münster (english);
highlighted by press releases of
Idw-online, EurekAlert!, Phys.org, ChemEurope.com, Azom.com, TechnologyNetworks.com, MyScience, PostUSnews, UpJobsNews, NewsBeezer.com, NewsFounded.com, Trueviralnews.com, 123HindiNews.com, Chemie.de (german), Krebs-Nachrichten (german), ChemEurope.com/fr (french), Quimica.es (spanish), ProzessVogel.de (german), Deporticos.co.cr (spanish).
412) A. Kaithal, T. Wagener, P. Bellotti, C. G. Daniliuc, L. Schlichter, F. Glorius,
Access to Unexplored 3D Chemical Space: cis-Selective AreneHydrogenation for the Synthesis of Saturated Cyclic Boronic Acids,
Angew. Chem. Int. Ed. 2022, 61 (32), e202206687; Angew. Chem. 2022, 134 (32), e202206687. DOIDedicated to Prof. David Milstein on the occasion of his 75th birthday
411) Z. Wang, M. Das, C. Gutheil, H. Osthues, F. Strieth-Kalthoff, A. Timmer, N. L. Doltsinis,* W. Wang,* L. Chi,* F. Glorius,*
Surface Modification with a Fluorinated N-Heterocyclic Carbene on Au: Effect on Contact Resistance in Organic Field Effect Transistors,
J. Mater. Chem. C 2022, 10, 8589-8595. DOI
410) R. Kleinmans,§ T. Pinkert,§ S. Dutta, T. O. Paulisch, H. Keum, C. G. Daniliuc, F. Glorius,
Intermolecular [2π+2σ]-photocycloaddition enabled by triplet energy transfer,
Nature 2022, 605, 477-482. DOI
§ These authors contributed equallyHighlighted by press release of WWU Münster (german);
highlighted by press release of WWU Münster (english);
highlighted by press releases of myscience.org, phys.org, azom.com, newsbreak.com, trueviralnews.com, LaboratoryEquipment, ChemEurope, The Galaxa Positor News (French), News.Sciencenet.cn, Idw online (german), Analytik.News (german).
409) F. Strieth-Kalthoff,§ F. Sandfort,§ M. Kühnemund, F. R. Schäfer, H. Kuchen, F. Glorius,
Machine Learning for Chemical Reactivity: The Importance of Failed Experiments,
Angew. Chem. Int. Ed. 2022, 61 (29), e202204647; Angew. Chem. 2022, 134 (29), e202204647. DOI
§ These authors contributed equally
Dedicated to the late Professor David A. EvansHighlighted by Nature Chem. 2022, 14, 973-975: Jacqueline M. Cole, The chemistry of errors;
highlighted by Nature 2024: Rachel Brazil, "Illuminating ‘the ugly side of science’: fresh incentives for reporting negative results". DOI
Chemistry World (Yield-predicting AI needs chemists to stop ignoring failed experiments);
ChemistryViews (More Data in Chemistry).Highlighted by press releases of Angew. Chem. Int. Ed., ChemEurope.com, EurekAlert!, DagoldNews, Idw (german), Solarify.eu (german), Chemie.de (german), Analytik.news (german), Process.Vogel (german), AusderWelt.de (german), Laborpraxis.vogel.de (german), Fr.Postsus.com (French), Quimica.es (spanish).
408) J. J. Navarro, M. Das, S. Tosoni,* F. Landwehr, M. Koy, M. Heyde,* G. Pacchioni, F. Glorius,* B. Roldan Cuenya,
Growth of N-Heterocyclic Carbene Assemblies on Cu(100) and Cu(111): from Single Molecules to Magic-Number Islands,
Angew. Chem. Int. Ed. 2022, 61 (30), e202202127; Angew. Chem. 2022, 134 (30), e202202127. DOI
407) K. Kajiwara,§ H. Osaki,§ S. Greßies, K. Kuwata, J. H. Kim, T. Gensch, Y. Sato, F. Glorius,* S. Yamaguchi,* M. Taki,*
A negative-solvatochromic fluorescent probe for visualizing intracellular distributions of fatty acid metabolites,
Nature Commun. 2022, 13, 2533. DOI
§ These authors contributed equally
406) H.-M. Huang,* P. Bellotti, F. Glorius*,
Merging Carbonyl Addition with Photocatalysis,
Acc. Chem. Res. 2022, 55, 1135-1147. DOI
405) L. Quach, S. Dutta, P. M. Pflüger, F. Sandfort, P. Bellotti, F. Glorius,
Visible-Light-Initiated Hydrooxygenation of Unactivated Alkenes - A Strategy for Anti-Markovnikov Hydrofunctionalization,
ACS Catal. 2022, 12, 2499-2504. DOI
404) B. J. Tyler,* R. Kassenböhmer, R. E. Peterson, D. T. Nguyen, M. Freitag, F. Glorius, B. J. Ravoo, H. F. Arlinghaus,
Denoising of Mass Spectrometry Images via Inverse Maximum Signal Factors Analysis,
Anal. Chem. 2022, 94, 2835-2843. DOI
403) H.-M. Huang,§ P. Bellotti,§ P.-P. Chen,§ K. N. Houk,* F. Glorius,*
Allylic C(sp3)―H Arylation of Olefins via Ternary Catalysis,
Nature Synth. 2022, 1, 59-68. DOI
§ These authors contributed equallyHighlighted in Nat. Synth. by Prof. Gabriel dos Passos Gomes (“Three catalysts tango with olefins”);
Highlighted by press release of WWU Münster (english);
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Highlighted by press releases of Idw-online, EurekAlert!,
ScienceDaily, Chemanager-online.com (German), DailyAdvent.com, Research-in-Germany.org, Azom.com, Chemie.de (German), Process.Vogel.de (German), Innovations-report.de (German), Solarify.eu (German), Citizenside.fr (French), Quimica.es (Spanish).
402) H.-M. Huang,§ P. Bellotti,§ J. E. Erchinger, T. O. Paulisch, F. Glorius,
Radical Carbonyl Umpolung Arylation via Dual Nickel Catalysis,
J. Am. Chem. Soc. 2022, 144, 1899-1909. DOI
§ These authors contributed equallyDedicated to the late Prof. Robert H. Grubbs
401) J. Ren,§ M. Freitag,§ Y. Gao,§ P. Bellotti, M. Das, B. Schulze Lammers, H. Mönig, Y. Zhang, C. G. Daniliuc, S. Du*, H. Fuchs*, F. Glorius,*
Reversible Self-Assembly of an N-Heterocyclic Carbene on Metal Surfaces,
Angew. Chem. Int. Ed. 2022, 61 (13), e202115104; Angew. Chem. 2022, 134 (13), e202115104. DOI
§ These authors contributed equally
400) S. Cembellín,* I. Maisuls, C. G. Daniliuc, H. Osthues, N. L. Doltsinis, C. A. Strassert, F. Glorius,
One-step synthesis of indolizino[3,4,5-ab]isoindoles by manganese(i)-catalyzed C–H activation: structural studies and photophysical properties,
Org. Biomol. Chem. 2022, 20, 796-800. DOI
399) A. Hamza,* D. Moock, C. Schlepphorst, J. Schneidewind, W. Baumann, F. Glorius*,
Unveiling a key catalytic pocket for the ruthenium NHC-catalysed asymmetric heteroarene hydrogenation,
Chem. Sci. 2022, 13, 985-995. DOI
398) J.-H. Ye, P. Bellotti, C. Heusel, F. Glorius,
Photoredox-Catalyzed Defluorinative Functionalizations of Polyfluorinated Aliphatic Amides and Esters,
Angew. Chem. Int. Ed. 2022, 61 (9), e202115456; Angew. Chem. 2022, 134 (9), e202115456. DOI
Highlighted in Synfacts 2022, 18, 0199. DOIDedicated to Professor Qi-Lin Zhou on the occasion of his 65th birthday
397) T. O. Paulisch, L. A. Mai, F. Strieth-Kalthoff, M. J. James, C. Henkel, D. M. Guldi,* F. Glorius,*
Dynamic kinetic sensitization of β-dicarbonyl compounds – Access to medium-sized rings via a De Mayo-type ring expansion,
Angew. Chem. Int. Ed. 2022, 61 (5), e202112695; Angew. Chem. 2022, 134 (5), e202112695. DOIFeatured in Organic Chemistry Highlights
396) L. F. B. Wilm, M. Das, D. Janssen-Müller, C. Mück-Lichtenfeld, F. Glorius,* F. Dielmann,*
Photoswitchable Nitrogen Superbases: Using Light for Reversible Carbon Dioxide Capture,
Angew. Chem. Int. Ed. 2022, 61 (3), e202112344; Angew. Chem. 2022, 134 (3), e202112344. DOI
Highlighted on ChemistryViewDedicated to Professor Gerhard Erker on the occasion of his 75th birthday
2021
395) Y. Liang,§ F. Strieth-Kalthoff,§ P. Bellotti, F. Glorius,
Catalytic one-carbon homologation of α-amino acids to α-amino aldehydes,
Chem Catal. 2021, 1, 1427-1436. DOI
Highlighted in Chem Catal. 2021, 1, 1354 by Prof. Stephen G. Newman (“Rapid access to β-amino aldehydes by a Ni/Ir dual-catalyzed homologation reaction”)§ These authors contributed equally
394) H. Wang, P. Bellotti, X. Zhang, T. O. Paulisch, F. Glorius,
A base-controlled switch of SO2 reincorporation in photocatalyzed radical difunctionalization of alkenes,
Chem 2021, 7, 3412-3424. DOI
393) S. Kriegler, T. O Paulisch, T. Wegner, F. Glorius,* R. Winter,*
Bipolar Imidazolium-Based Lipid Analogues for Artificial Archaeosomes,
Langmuir 2021, 37, 11996-12006. DOI
392) T. Hu, L. Lückemeier, C. Daniliuc, F. Glorius,
Ru-NHC-Catalyzed Asymmetric Hydrogenation of 2-Quinolones to Chiral 3,4-Dihydro-2-Quinolones,
Angew. Chem. Int. Ed. 2021, 60, 23193-23196; Angew. Chem. 2021, 133, 23377-23381. DOIDedicated to Professor Dieter Hoppe on the occasion of his 80th birthday
391) S. Dery, P. Bellotti, T. Ben-Tzvi, M. Freitag, T. Shahar, A. Cossaro, A. Verdini, L. Floreano, F. Glorius*, E. Gross,*
Influence of N-Substituents on the Adsorption Geometry of OH-Functionalized Chiral N-Heterocyclic Carbenes,
Langmuir 2021, 37, 10029-10035. DOI
390) P. Bellotti, M. Koy, M. N. Hopkinson,* F. Glorius,*
Recent advances in the chemistry and applications of N-heterocyclic carbenes,
Nat. Rev. Chem. 2021, 5, 711-725. DOI
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389) M. Franz, S. Chandola, M. Koy, R. Zielinski, H. Aldahhak, M. Das, M. Freitag, U. Gerstmann, D. Liebig, A. K.Hoffmann, M. Rosin, W. G. Schmidt, C. Hogan, F. Glorius,* N. Esser,* M. Dähne,*
Controlled growth of ordered monolayers of N-heterocyclic carbenes on silicon,
Nature Chem. 2021, 13, 828-835. DOI
Free SharedIt-LinkHighlighted by press release of WWU Münster (english);
Highlighted by press release of WWU Münster (german);
Highlighted by press releases of idw-online, ScienceDaily.com, Phys.org, Hitech.glitz.com, Azom.com, Computational chemistry daily, PennyNews.com, Analytiknews (german), CitizenSide.com (french), Science-things.com (spanish), CNR.it (italian).
388) A. L. L. Matos, F. Keller, T. Wegner, C. E. Cadena del Castillo, D. Grill, S. Kudruk, A. Spang, F. Glorius*, A. Heuer*, V. Gerke*,
CHIMs are versatile cholesterol analogs mimicking and visualizing cholesterol behavior in lipid bilayers and cells,
Commun. Biol. 2021, 4, Article number 720. DOI, OA Link (Springer Nature SharedIt)
387) G. Tan,§ I. Maisuls,§ F. Strieth-Kalthoff, X. Zhang, C. Daniliuc, C. A. Strassert*, F. Glorius,*
AIE-Active Difluoroboron Complexes with N,O-Bidentate Ligands: Rapid Construction by Copper-Catalyzed C−H Activation,
Adv. Sci. 2021, 8, 202101814 (open access). DOI
§ These authors contributed equally.
386) K. I. Burton, I. Elser, A. E. Waked, T. Wagener, R. J. Andrews, F. Glorius,* D. W. Stephan,*
Bipyridinium and Phenanthrolinium Dications for Metal-Free Hydrodefluorination: Distinctive Carbon-Based Reactivity,
Chem. Eur. J. 2021, 27, 11730-11737. DOI
385) T. Pinkert, M. Das, M. L. Schrader, F. Glorius,
The Use of Strain-Release for the Diastereoselective Construction of Quaternary Carbon Centers,
J. Am. Chem. Soc. 2021, 143, 7648-7654. DOI
384) G. Tan, M. Das, I. Maisuls, C. A. Strassert, Frank Glorius,
Rhodium-Catalyzed Dealkenylative Arylation of Alkenes with Arylboronic Compounds,
Angew. Chem. Int. Ed. 2021, 60, 15650-15655; Angew. Chem. 2021, 133, 15780-15785. DOIDedicated to Prof. Christian Bruneau
383) M. Koy, P. Bellotti, M. Das, F. Glorius,
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces,
Nature Catal. 2021, 4, 352-363. DOI
Free SharedIt link (view only)
382) H.-M. Huang,§ P. Bellotti,§ J. Ma, T. Dalton, F. Glorius,
Bifunctional Reagents in Organic Synthesis,
Nature Rev. Chem. 2021, 5, 301-321. DOI
Free SharedIt link (view only)
§ These authors contributed equally.
381) D. Moock, T. Wagener, T. Hu, T. Gallagher, F. Glorius,
Enantio- and Diastereoselective, Complete Hydrogenation of Benzofurans by Cascade Catalysis,
Angew. Chem. Int. Ed. 2021, 60, 13677-13681; Angew. Chem. 2021, 133, 13791-13796. DOI
Selected as Hot Paper by publisher.Dedicated to Prof. Pierre H. Dixneuf
380) A. Heusler,§ J. Fliege,§ T. Wagener, F. Glorius,
Substituted Dihydropyridine Synthesis by Dearomatization of Pyridines,
Angew. Chem. Int. Ed. 2021, 60, 13793-13797; Angew. Chem. 2021, 133, 13912-13916. DOI
§ These authors contributed equally.
Selected as Hot Paper by publisher;
Highlighted by Organic Process Research & DevelopmentDedicated to Prof. Robert H. Morris
379) A. Theodoridis, G. Papamokos, M. P. Wiesenfeldt, M. Wollenburg, K. Müllen, F. Glorius,* G. Floudas*,
Polarity Matters: Dielectric Relaxation in All-cis-Multifluorinated Cycloalkanes,
J. Chem. Phys. B 2021, 125, 3700-3709. DOI
378) J. Ma,§ S. Chen,§ P. Bellotti,§ R. Guo, F. Schäfer, A. Heusler, X. Zhang, C. Daniliuc, M. K. Brown,* K. N. Houk,* F. Glorius,*
Photochemical Intermolecular Dearomative Cycloaddition of Bicyclic Azaarenes with Alkenes,
Science 2021, 371, 1338-1345. DOI
§ These authors contributed equally.Perspective by Prof. Valerie Schmidt (UCSD): Getting excited about cycloadditions, Science 2021, 371, 1313;
Highlighted by ChemieXtra 2021, (6), 12, LINK;
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Highlighted by Organic Chemistry Portal;
Highlighted by press releases of ScienceMag.org, Eurekalert!, Jioforme.com, Teknodate.com, Technologynetworks.com, Scienceboard.net, Scitechdaily.com, C&EN,
LosAngelesDailyNewswire.com, Phys.org, Sciencesprings.wordpress.com, Ministere des Finances Laos,
Idw-online (german), Process.Vogel.de (german), Chemie.de (german), Chemiepharma-innovation-ch (german), News-medical.net (Spanish),
Technoguide.fr (French), Finance.sina.com (Chinese), Paper.science.net (Chinese).
377) J.-H. Ye, P. Bellotti, T. O. Paulisch, C. G. Daniliuc, F. Glorius,
Visible-Light-Induced Cycloaddition of α-Ketoacylsilanes with Imines: Facile Access to β-Lactams,
Angew. Chem. Int. Ed. 2021, 60, 13671-13676; Angew. Chem. 2021, 133, 13785-13790. DOI
Selected as Hot Paper by publisher
Dedicated to Professor Peter Kündig on the occasion of his 75th birthday.
376) M. P. Wiesenfeldt,§ D. Moock,§ D. Paul,§ F. Glorius,
Enantioselective Hydrogenation of Annulated Arenes: Controlled Formation of Multiple Stereocenters in Adjacent Rings,
Chem. Sci. 2021, 12, 5611-5615. DOI
§ These authors contributed equally.
375) T. Dalton,§ S. Greßies,§ M. Das, M. Niehues,§§ M. L. Schrader,§§ C. Gutheil,§§ B. J. Ravoo, F. Glorius,
Silver-Catalysed Hydroarylation of Highly Substituted Styrenes,
Angew. Chem. Int. Ed. 2021, 60, 8537-8541; Angew. Chem. 2021, 133, 8616-8623. DOI
§,§§ These authors contributed equally.
Selected as Hot Paper by publisher.In memoriam: Dr. Steven Cooper (1971-2019)
374) T. Wagener,§ L. Lückemeier,§ C. G. Daniliuc, F. Glorius,
Interrupted Pyridine Hydrogenation: Asymmetric Synthesis of δ-Lactams,
Angew. Chem. Int. Ed. 2021, 60, 6425-6429; Angew. Chem. 2021, 133, 6496-6500. DOI
§ These authors contributed equally.
Dedicated to Professor David A. Evans on the occasion of his 80th birthday.Highlighted by X-Mol, Org. Process Res. Dev.
373) R. Kleinmans, L. E. Will, J. L. Schwarz, F. Glorius,
Photoredox-enabled 1,2-dialkylation of α-substituted acrylates via Ireland–Claisen rearrangement,
Chem. Sci. 2021, 12, 2816-2822. DOI
Selected as Hot Paper.
Highlighted by Synfacts 2021, 17, 0305. DOI
372) J.-P. Schmiegel, R. Nölle, J. Henschel, L. Quach, S. Nowak, M. Winter, F. Glorius,* T. Placke,*
Case study of N-carboxyanhydrides in silicon-based lithium ion cells as a guideline for systematic electrolyte additive research,
Cell Rep. Phys Sci. 2021, 2, Article 100327. DOI
371) S. Mondal, T. Pinkert, C. G. Daniliuc, F. Glorius,
Regioselective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C–H Alkynylation,
Angew. Chem. Int. Ed. 2021, 60, 5688-5672; Angew. Chem. 2021, 133, 5752-5756. DOI
370) T. Dalton, T. Faber, F. Glorius,
C-H Activation: towards sustainability and applications,
ACS Cent. Sci. 2021, 7, 245-261. DOI
369) P. Bellotti, M. Koy, C. Gutheil, S. Heuvel, F. Glorius,
Three-component three-bond forming cascade via palladium photoredox catalysis,
Chem. Sci. 2021, 12, 1810-1817. DOI
368) T. Patra, M. Das, C. G. Daniliuc, F. Glorius,
Metal-free, photosensitized oxyimination of unactivated alkenes with bifunctional oxime carbonates,
Nature Catal. 2021, 4, 54-61. DOIHighlighted by Synfacts 2021, 17, 0319 (by Nobel laureate List), DOI;
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ScienceDaily, Bioengineer.org, ScienMag, Pressaggregate.com, 15minutenews.com, Idw-online (german),
Lebensmittel-Biotechnologie (german), Innovations-Report (german), Genius-Science.fr (french).
367) S. Greßies,§ M. Ito,§ M. Sakai, H. Osaki, J. H. Kim, T. Gensch, C. Daniliuc, N. Ando, S. Yamaguchi,* F. Glorius,*
Twofold C–H Activation Enables Synthesis of a Diazacoronene‐type Fluorophore with Near Infrared Emission through Isosteric Replacement,
Chem. Eur. J. 2021, 27, 2753-2759. DOI
§ These authors contributed equally.
Highlighted by Synfacts 2021, 17, 0035. DOI
366) H.-M. Huang, P. Bellotti, C. Daniliuc, F. Glorius,
Radical Carbonyl Propargylation by Dual Catalysis,
Angew. Chem. Int. Ed. 2021, 60, 2464-2471; Angew. Chem. 2021, 133, 2494-2501. DOI
This is our 100th publication in Angewandte Chemie and we are happy to dedicate it to Prof. Carsten Bolm.
2020
365) F. Schäfers, L. Quach, J. L. Schwarz, M. Saladrigas, C. G. Daniliuc, F. Glorius,
Direct Access to Monoprotected Homoallylic 1,2-Diols via Dual Chromium/Photoredox Catalysis,
ACS Catal. 2020, 10, 11841-11847. DOI
364) T. Wagener, A. Heusler, Z. Nairoukh, K. Bergander, C. G. Daniliuc, F. Glorius,
Accessing (Multi)Fluorinated Piperidines Using Heterogeneous Hydrogenation,
ACS Catal. 2020, 10, 12052-12057. DOI
Highlighted in Synfacts 2020, 16, 1439. DOI
Highlighted in Org. Process Res. Dev. 2020, 24, 2383-2393. DOI
363) M. Wollenburg, A. Heusler, K. Bergander, F. Glorius,
trans-Selective and Switchable Arene Hydrogenation of Phenol Derivatives,
ACS Catal. 2020, 10, 11365-11370. DOI
Highlighted by Synfacts 2021, 17, 0048. DOI
362) S. Amirjalayer,* A. Bakker, M. Freitag, F. Glorius, H. Fuchs,
Cooperation of N‐Heterocyclic Carbenes on a Gold Surface,
Angew. Chem. Int. Ed. 2020, 59, 21230-21235; Angew. Chem. 2020, 132, 21416-21422. DOI
Highlighted by press release of WWU Münster (english);
Highlighted by press release of WWU Münster (german);
Highlighted by press releases of ChemEurope.com, ScienceDaily.com, Myscience.org, Pro-Physik.de (german), Quimica.es (spanish).
361) P. M. Pflüger, F. Glorius,
Molecular Machine Learning: The Future of Synthetic Chemistry?,
Angew. Chem. Int. Ed. 2020, 59, 18860-18865; Angew. Chem. 2020, 132, 19020-19025. DOI
360) T. O. Paulisch, S. Bornemann, M. Herzog, S. Kudruk, L. Roling, A. L. Linard Matos, H.-J. Galla, V. Gerke,* R. Winter,* F. Glorius,*
An Imidazolium‐based Lipid Analogue as Gene Transfer Agent,
Chem. Eur. J. 2020, 26, 17176-17182. DOI
359) F. Strieth-Kalthoff, F. Glorius,
Triplet Energy Transfer Photocatalysis – Unlocking the Next Level,
Chem 2020, 6, 1888-1903. DOI
358) G. Tan, M. L. Schrader, C. Daniliuc, F. Strieth-Kalthoff, F. Glorius,
C-H Activation Based Copper-Catalyzed One-Shot Synthesis of Organic Difluoroboron Complexes,
Angew. Chem. Int. Ed. 2020, 59, 21541-21545; Angew. Chem. 2020, 132, 21725-21729. DOI
357) F. Strieth-Kalthoff, F. Sandfort, M. H. S. Segler, F. Glorius,
Machine Learning the Ropes: Principles, Applications and Directions in Synthetic Chemistry,
Chem. Soc. Rev. 2020, 49, 6154-6168. DOI
356) H.-M. Huang, P. Bellotti, F. Glorius,
Transition metal-catalysed allylic functionalization reactions involving radicals,
Chem. Soc. Rev. 2020, 49, 6186-6197. DOI
355) C. Gelis, A. Heusler, Z. Nairoukh, F. Glorius,
Catalytic transfer hydrogenation of arenes and heteroarenes,
Chem. Eur. J. 2020, 26, 14090-14094. DOI
354) J. Ren, M. Freitag, C. Schwermann, A. Bakker, S. Amirjalayer, A. Rühling, H.-Y. Gao, N. L. Doltsinis*, F. Glorius*, H. Fuchs*,
A Unidirectional Surface-Anchored N-Heterocyclic Carbene Rotor,
Nano Lett. 2020, 20, 5922-5928. DOI
353) H.-M. Huang, P. Bellotti, P. M. Pflüger, J. L. Schwarz, B. Heidrich, F. Glorius,
A Three-Component, Interrupted Radical Heck/Allylic Substitution Cascade Involving Unactivated Alkyl Bromides,
J. Am. Chem. Soc. 2020, 142, 10173-10183. DOI
Highlighted twice in Organic Chemistry Portal (Abstracts and Highlights 2021)
352) D. Moock, M. P. Wiesenfeldt, M. Freitag, S. Muratsugu, S. Ikemoto, R. Knitsch, J. Schneidewind, W. Baumann, A. H. Schäfer, A. Timmer, M. Tada, M. R. Hansen, F. Glorius,
Mechanistic Understanding of the Heterogeneous, Rhodium-Cyclic (Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation,
ACS Catal. 2020, 10, 6309-6317. DOI
351) S. Bornemann, M. Herzog, L. Roling, T. Paulisch, D. Brandis, S. Kriegler, H.-J. Galla, F. Glorius,* R. Winter,*
lnteraction of imidazolium-based lipids with phospholipid bilayer membranes of different complexity,
Phys. Chem. Chem. Phys. 2020, 22, 9775-9788. DOI
350) M. Wollenburg, J. Bajohr, A. D. Marchese, A. Whyte, F. Glorius,* M. Lautens,*
Palladium-Catalyzed Disilylation and Digermanylation of Alkene Tethered Aryl Halides: Direct Access to Versatile Silylated and Germanylated Heterocycles,
Org. Lett. 2020, 22, 3679-3683. DOI
349) D. T. Nguyen,§ M. Freitag,§ C. Gutheil, K. Sotthewes, B. J. Tyler, M. Böckmann, M. Das, F. Schlüter, N. L. Doltsinis, H. F. Arlinghaus, B. J. Ravoo,* F. Glorius,*
An Arylazopyrazole Based N-Heterocyclic Carbene as Photoswitch on Gold Surfaces: Light-Switchable Wettability, Work Function and Conductance,
Angew. Chem. Int. Ed. 2020,59, 13651-13656; Angew. Chem. 2020,132, 13754-13759. DOI
§ These authors contributed equally.Dedicated to Prof. F. Ekkehardt Hahn on the occasion of his 65th birthday.
348) A. Bakker,§ M. Freitag,§ E. Kolodzeiski, P. Bellotti, A. Timmer, J. Ren, B. Schulze Lammers, D. Moock, H. W. Roesky, H. Mönig, S. Amirjalayer, H. Fuchs,* F. Glorius,*
An Electron-rich Cyclic (Alkyl)(Amino) Carbene on Au(111), Ag(111) and Cu(111) Surfaces,
Angew. Chem. Int. Ed. 2020, 59, 13643-13646; Angew. Chem. 2020, 132, 13745-13749 (selected as VIP). DOI
§ These authors contributed equally.Dedicated to Prof. Albert Eschenmoser on the occasion of his 95th birthday.
347) Z. Nairoukh,§* F. Strieth-Kalthoff,§ K. Bergander, F. Glorius,*
Understanding the Conformational Behavior of Fluorinated Piperidines: The Origin of the Axial‐F Preference,
Chem. Eur. J. 2020, 26, 6141-6146. DOI
§ These authors contributed equally.Dedicated to Prof. Bernd Giese on the occasion of his 80th birthday.
346) F. Sandfort, T. Knecht, T. Pinkert, C. G. Daniliuc, F. Glorius,
Site-Selective Thiolation of (Multi)halogenated Heteroarenes,
J. Am. Chem. Soc. 2020, 142, 6913-6919. DOI
Highlighted by ChemistryViews.
Highlighted in Synfacts 2020, 16, 0869. DOI
345) W. Li,* T. Wagener, L. Hellmann, C. G. Daniliuc, C. Mück-Lichtenfeld, J. Neugebauer,* F. Glorius,*
Design of Ru(II)-NHC-Diamine Precatalysts Directed by Ligand Cooperation: Applications and Mechanistic Investigations for Asymmetric Hydrogenation,
J. Am. Chem. Soc. 2020, 142, 7100-7107. DOI
Highlighted in Synfacts 2020, 16, 0809. DOI
344) A. D. Marchese, M. Wollenburg, B. Mirabi, X. Abel-Snape, A. Whyte, F. Glorius,* M. Lautens*,
Nickel-Catalyzed Enantioselective Carbamoyl Iodination: A Surrogate for Carbamoyl Iodides,
ACS Catal. 2020, 10, 4780-4785. DOI
343) F. Sandfort,§ F. Strieth-Kalthoff,§ M. Kühnemund,§ C. Beecks, F. Glorius,*
A Structure-Based Platform for Predicting Chemical Reactivity,
Chem 2020, 6, 1379-1390. DOI
ChemRxiv (Preprint) 2019. DOI
§ All three authors contributed equally.Highlighted by press release of WWU Münster (english);
Highlighted by press release of WWU Münster (german);
Highlighted by press releases of Chemistryworld.com, EurekAlert.org, ChemEurope.com, Sciencedaily.com, Phys.org, Rasayanika.com, Myscience.org, X-mol.com, Scienmag.com, Spektrum.de (German), Chemie.de (German), Git-labor.de (German), Process.Vogel.de (German), Nouvelles du monde (French), BigData-Insider.de (German), Diário Carioca (Portugese);
Highlighted by Spektrum der Wissenschaft 2020, (4), 32-34 (CHEMIE
REAKTIONSVORHERSAGE MIT KI);
Highlighted by Nature Reviews Chemistry 2020 (Gabriella Graziano)
342) J. Ma, F. Schäfers, C. Daniliuc, K. Bergander, C. A. Strassert, F. Glorius,
Gadolinium Photocatalysis: Dearomative [2+2] Cycloaddition/Ring-Expansion Sequence with Indoles,
Angew. Chem. Int. Ed. 2020, 59, 9639-9645; Angew. Chem. 2020, 132, 9726-9735. DOI
Highlighted by ChemistryViews.
341) H.-M. Huang , M. Koy, E. Serrano, P. M. Pflüger, J. L. Schwarz, F. Glorius,
Catalytic radical generation of π-allylpalladium complexes,
Nature Catalysis 2020, 3, 393-400. DOI SharedIt linkHighlighted by press release of WWU Münster (english);
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Highlighted by press releases of Sciencedaily.com, phys.org, EurekAlert.org, Innovations-Report.de (German), Technologik.fr (French), enciclopediavirtual.com.br (Portugese), Chemie.de (German), Chemeurope.com, Analytik.News (German).
340) M. A. Stoffels, F. J. R. Klauck, T. Hamadi, F. Glorius,* J. Leker,*
Technology Trends of Catalysts in Hydrogenation Reactions: A Patent Landscape Analysis,
Adv. Synth. Catal. 2020, 362, 1258-1274. DOI
339) J. L. Schwarz,§ R. Kleinmans,§ T. O. Paulisch, F. Glorius,
1,2-Amino Alcohols via Cr/Photoredox Dual-Catalyzed Addition of α‑Amino Carbanion Equivalents to Carbonyls,
J. Am. Chem. Soc. 2020, 142, 2168-2174. DOI
§ Both authors contributed equally.
338) J. L. Schwarz, H.-M. Huang, T. O. Paulisch, F. Glorius,
Dialkylation of 1,3-Dienes by Dual Photoredox and Chromium Catalysis,
ACS Catal. 2020, 10, 1621-1627. DOI
337) S. Singha,§ E. Serrano,§ S. Mondal, C. G. Daniliuc, F. Glorius,
Diastereodivergent synthesis of enantioenriched α,β-disubstituted-γ-butyrolactones via cooperative N-heterocyclic carbene/Ir catalysis,
Nature Catalysis 2020, 3, 48-54. DOI
§ Both authors contributed equally.
Highlighted by press release of WWU Münster (english);
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Science Daily, myscience.de, chemeurope.com, Process, chemie.de (german), Innovations-Report (german), and Quimica.es (spanish);
Featured in Org. Chem. Highlights: Arrays of Stereogenic Centers.
336) T. Patra, P. Bellotti, F. Glorius,
Photosensitized intermolecular carboimination of alkenes through persistent radical effect,
Angew. Chem. Int. Ed. 2020, 59, 3172-3177; Angew. Chem. 2020, 132, 3198-3203. DOI
Highlighted in Synform by Dr. Matteo Zanda: Synform 2020, 06, A86-A87.
335) M. Koy,§ P. Bellotti,§ F. Katzenburg, C. Daniliuc, F. Glorius,
Synthesis of All‐Carbon Quaternary Centers by Palladium‐Catalyzed Olefin Dicarbofunctionalization,
Angew. Chem. Int. Ed. 2020, 59, 2375-2379; Angew. Chem. 2020, 132, 2395-2399. DOI
§ Both authors contributed equally.
Dedicated to Roland Winter on the occasion of his 65th birthday
334) T. O. Paulisch,§ F. Strieth-Kalthoff,§ C. Henkel, L. Pitzer, D. M. Guldi, F. Glorius,
Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds,
Chem. Sci. 2020, 11, 731-736. DOI
§ Both authors contributed equally.
333) S. Cembellín, T. Dalton, T. Pinkert, F. Schäfers, F. Glorius,
Highly Selective Synthesis of 1,3-Enynes, Pyrroles, and Furans by Manganese(I)-Catalyzed C–H Activation,
ACS Catalysis 2020, 10, 197-202. DOI
2019
332) J. Ma, F. Strieth-Kalthoff, T. Dalton, M. Freitag, J. L. Schwarz, K. Bergander, C. Daniliuc, F. Glorius,
Direct Dearomatization of Pyridines via an Energy-Transfer-Catalyzed Intramolecular [4+2] Cycloaddition,
Chem 2019, 5, 2854-2864 (free featured article). DOIHighlighted by L. Chang, Y. Chen, Z. Zuo,* Chem 2019, 5, 2744-2746. DOI
Highlighted by press release of WWU Münster (english);
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Highlighted by press releases of Phys.org, EurekAlert,
Science Daily, PhysicsNews, LABO (german), Innovations-Report, myscience.de, chemeurope.com, chemie.de (german), and GIT Laborportal (german).
331) K. Goossens,* L. Rakers, B. Heinrich, G. Ahumada, T. Ichikawa, B. Donnio, T.J. Shin, C. W. Bielawski,* F. Glorius,*
1,2,3,4,5-Pentaalkylimidazolium salts: synthesis, thermal behavior and induction of supramolecular, anisotropic, organic ionic plastic crystal mesophases,
Chem. Mater. 2019, 31, 9593-9603. DOI
330) M. Teders, S. Bernard, K. Gottschalk, L. J. Schwarz, E. Standley, E. Decuypere, C. Daniliuc, D. Audisio, F. Taran,* F. Glorius,*
Accelerated Discovery in Photocatalysis by a Combined Screening Approach Involving MS-Tags,
Org. Lett. 2019, 21, 9747-9752. DOI
329) J.-H. Ye, L. Quach, T. Paulisch, F. Glorius,
Visible-Light-Induced, Metal-Free Carbene Insertion into B–H Bonds between Acylsilanes and Pinacolborane,
J. Am. Chem. Soc. 2019, 141, 16227-16231. DOI
328) P. Bunse, C. Schlepphorst, F. Glorius, M. Kitamura, B. Wünsch,*
Short and Atom-Economic Enantioselective Synthesis of the σ1-Receptor Ligands (S)- and (R)-Fluspidine—Important Tools for Positron Emission Tomography Studies,
J. Org. Chem. 2019, 84, 13744-13754. DOI
327) L. Pitzer,§ J. L. Schwarz,§ F. Glorius,
Reductive radical-polar crossover: Traditional electrophiles in modern radical reactions,
Chem. Sci. 2019, 10, 8285-8291. DOI
§ Both authors contributed equally.
326) T. Pinkert, T. Wegner, S. Mondal, F. Glorius,
Intermolecular 1,4–Carboamination of Conjugated Dienes Enabled by Cp*RhIII‐Catalyzed C–H Activation,
Angew. Chem. Int. Ed. 2019, 58, 15041-15045; Angew. Chem. 2019, 131, 15183-15187. DOI
325) L. Anhäuser, M. Teders, A. Rentmeister,* F. Glorius,*
Bio-additive-based screening: toward evaluation of the biocompatibility of chemical reactions,
Nature Protoc. 2019, 14, 2599-2626. DOI
324) F. Strieth-Kalthoff, C. Henkel, M. Teders, A. Kahnt, W. Knolle, A. Gómez-Suárez, K. Dirian, W. Alex, K. Bergander, C. G. Daniliuc, B. Abel, D. M. Guldi,* F. Glorius,*
Discovery of Unforeseen Energy-Transfer-Based Transformations Using a Combined Screening Approach,
Chem 2019, 5, 2183-2194. DOI
Highlighted by press release of WWU Münster (english);
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Highlighted by ChemieXtra 2019, (12), 12-14;
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Informationsdienst Wissenschaft idw, ScienceDaily, EurekAlert!, Phys.org, ScienceWorldReport, Myscience.de.
323) Q. Lu, S. Mondal, S. Cembellín, S. Greßies, F. Glorius,
Site-selective C–H Activation and Regiospecific Annulation Using Propargylic Carbonates,
Chem. Sci. 2019, 10, 6560-6564. DOI
322) C. Mühlen, J. Linde, L. Rakers, T. T. Y. Tan, F. Kampert, F. Glorius,* F. E. Hahn,*
Synthesis of Iron(0) Complexes Bearing Protic NHC Ligands: Synthesis and Catalytic Activity,
Organometallics 2019, 38, 2417-2421. DOI
321) T. Patra, S. Mukherjee, J. Ma, F. Strieth-Kalthoff, F. Glorius,
Visible-light photosensitized aryl and alkyl decarboxylative carbon-heteroatom and carbon-carbon bond formations,
Angew. Chem. Int. Ed. 2019, 58, 10514-10520; Angew. Chem. 2019, 131, 10624-10630. DOI
(ChemRxiv 2019, DOI).
320) M. J. James, F. Strieth-Kalthoff, F. Sandfort, F. J. R. Klauck, F. Wagener, F. Glorius,
Visible-Light-Mediated Charge Transfer Enables C–C Bond Formation with Traceless Acceptor Groups,
Chem. Eur. J. 2019, 25, 8240-8244. DOI
Dedicated to Richard J. K. Taylor on the occasion of his 70th birthdayPlease, see also: Varinder Aggarwal et al., Angew. Chem. Int. Ed. 2019, early view: Catalyst‐Free Deaminative Functionalizations of Primary Amines by Photoinduced Single‐Electron Transfer. DOI
319) M. N. Hopkinson,* F. Glorius,*
An Overview of NHCs,
in N-Heterocyclic Carbenes in Organocatalysis (Ed. A. T. Biju); Wiley-VCH, Weinheim, 2019, Chapter 1, p. 1-36.
318) L. Pitzer,§ F. Schäfers,§ F. Glorius,
Rapid Assessment of the Reaction Condition-Based Sensitivity of Chemical Transformations,
Angew. Chem. Int. Ed. 2019, 58, 8572-8576; Angew. Chem. 2019, 131, 8660-8664. DOI
§ Both authors contributed equally.
Dedicated to Prof. K. Barry SharplessPlease, kindly check it out. This conditions-based sensitivity screen nicely complements the additive-based robustness screen. For a free-to-use template of the radar diagram, see this link.
Highlighted by Nature Chemistry. DOI
317) T. Knecht,§ S. Mondal,§ J.-H. Ye, M. Das, F. Glorius,
Intermolecular, Branch-Selective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C–H Amidation,
Angew. Chem. Int. Ed. 2019, 58, 7117-7121; Angew. Chem. 2019, 131, 7191-7195. DOI
§ Both authors contributed equally.
Dedicated to Prof. Yitzhak Apeloig on the occasion of his 75th birthdayPlease, see also: H. Lei, T. Rovis, J. Am. Chem. Soc. 2019, 141, 2268. DOI
316) E. E. Lin, J.-Q. Wu, F. Schäfers, X.-X. Su, K.-F. Wang, J.-L. Li, Y. Chen, X. Zhao, H. Ti, Q. Li, T.-M. Ou, F. Glorius, H. Wang,*
Regio- and stereoselective synthesis of tetra- and triarylethenes by N-methylimidodiacetyl boron-directed palladium-catalysed three-component coupling,
Commun. Chem. 2019, 2, 34. DOI
315) J. Henschel, L. Schwarz, F. Glorius, M. Winter, S. Nowak,*
Further insights into structural diversity of phosphorus-based decomposition products in lithium ion battery electrolytes via liquid chromatographic techniques hyphenated to ion trap - time of flight mass spectrometry,
Analytical Chemistry 2019, 91, 3980-3988. DOI
314) M. P. Wiesenfeldt, Z. Nairoukh, T. Dalton, F. Glorius,
Selective Arene Hydrogenation Provides Direct Access to Saturated Carbo‐ and Heterocycles,
Angew. Chem. Int. Ed. 2019, 58, 10460-10476; Angew. Chem. 2019, 131, 10570-10586. DOI
Dedicated to Prof. Ryōji Noyori on the occasion of his 80th birthday
313) K. Goossens,§ L. Rakers,§ T. J. Shin, R. Honeker, C. W. Bielawski,* F. Glorius,*
Substituted Azolium Disposition: Examining the Effects of Alkyl Placement on Thermal Properties,
Crystals 2019, 9, 34. DOI
§ Both authors contributed equally.
312) T. Knecht, T. Pinkert,§ T. Dalton,§ A. Lerchen, F. Glorius,
Cp*RhIII-Catalyzed Allyl–Aryl Coupling of Olefins and Arylboron Reagents Enabled by C(sp3)–H Activation,
ACS Catal. 2019, 9, 1253-1257. DOI
§ Both authors contributed equally.
311) Z. Nairoukh , M. Wollenburg, C. Schlepphorst, K. Bergander, F. Glorius,
The formation of all-cis-(multi)fluorinated piperidines by a dearomatization–hydrogenation process,
Nature Chem. 2019, 11, 264-270. DOI, OA Link (Springer Nature SharedIt)
Highlighted by Synfacts 2019, 15, 0283;
Highlighted by press release of WWU Münster (english);
Highlighted by press release of WWU Münster (german);
Highlighted by ChemieXtra 2019, (6), 16;
Highlighted by press releases of EurekAlert; Informationsdienst Wissenschaft idw, Chemie.de, ScienceDaily, innovations-report, Phys.org, Research-in-Germany, Wissenschaftler.de, Analytiker.de, Tunis Daily News, Chemical Processing and World of Chemicals.See also the following link regarding the commercialization of the hydrogenation of fluoroarenes by Provendis GmbH.
310) F. J. R. Klauck, H. Yoon, M. J. James, M. Lautens,* F. Glorius,*
Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals,
ACS Catal. 2019, 9, 236-241. DOI
309) M. Wollenburg,§ D. Moock,§ F. Glorius,
Hydrogenation of Borylated Arenes,
Angew. Chem. Int. Ed. 2019, 58, 6549-6553; Angew. Chem. 2019, 131, 6621-6625. DOI
§ Both authors contributed equally.
308) M. Freitag,§ N. Möller,§ A. Rühling, C. A. Strassert, B. J. Ravoo,* F. Glorius,*
Photocatalysis in the dark: Near infrared light driven photoredox catalysis by an upconversion nanoparticle/photocatalyst system,
ChemPhotoChem. 2019, 3, 24-27. DOI
§ Both authors contributed equally.
2018
307) F. Sandfort,§ F. Strieth-Kalthoff,§ F. J. R. Klauck, M. J. James, F. Glorius,
Deaminative Borylation of Aliphatic Amines Enabled by Visible Light Excitation of an Electron-Donor-Acceptor Complex,
Chem. Eur. J. 2018, 24, 17210-17214. DOI
§ Both authors contributed equally.
Paper was most accessed from 10/2018-09/2019.
306) L. Pitzer,§ F. Sandfort,§ F. Strieth-Kalthoff, F. Glorius,
Carbonyl-Olefin Cross-Metathesis Through a Visible-Light-Induced 1,3-Diol Formation and Fragmentation Sequence,
Angew. Chem. Int. Ed. 2018, 57, 16219-16223; Angew. Chem. 2018, 130, 16453-16457. DOI
§ Both authors contributed equally.
305) P. Tegeder,§ M. Freitag,§ K. M. Chepiga, S. Muratsugu, N. Möller, S. Lamping, M. Tada, F. Glorius,* B. J. Ravoo,*
N-Heterocyclic Carbene-Modified AuPd Alloy Nanoparticles and their Application as Biomimetic and Heterogeneous Catalysts,
Chem. Eur. J. 2018, 24, 18682-18688. DOI
§ Both authors contributed equally.
Selected as hot paper by Chemistry - A European Journal
304) J. L. Schwarz,§ F. Schäfers,§ A. Tlahuext-Aca, L. Lückemeier, F. Glorius,
Diastereoselective Allylation of Aldehydes by Dual Photoredox and Chromium Catalysis,
J. Am. Chem. Soc. 2018, 140, 12705-12709. DOI
§ Both authors contributed equally.
303) C. Zhu,§ T. Pinkert,§ S. Greßies, F. Glorius,
One-Pot C−H Formylation Enabled by Relay Catalysis of Manganese(I) and Iron(III),
ACS Catal. 2018, 8, 10036-10042. DOI
§ Both authors contributed equally.
302) A. Bakker, A. Timmer, E. Kolodzeiski, M. Freitag, H. Y. Gao, H. Mönig, S. Amirjalayer,* F. Glorius,* H. Fuchs,*
Elucidating the binding modes of N-heterocyclic carbenes on a gold surface,
J. Am. Chem. Soc. 2018, 140, 11889-11892. DOI
301) A. Lerchen, T. Knecht, M. Koy, J. B. Ernst, K. Bergander, C. G. Daniliuc, F. Glorius,
Non-Directed Cross-Dehydrogenative (Hetero)arylation of Allylic C(sp3)–H bonds enabled by C–H activation,
Angew. Chem. Int. Ed. 2018, 57, 15248-15253; Angew. Chem. 2018, 130, 15468-15472. DOI
Selected as Hot Paper by Angewandte Chemie;
Highlighted in Synfacts 2018, 14, 1176.
300) L. Rakers, F. Schäfers, F. Glorius,
In water & under mild conditions: α-Alkylation of Ketones with Alcohols by Phase-Transfer-Assisted Borrowing Hydrogen Catalysis,
Chem. Eur. J. 2018, 24, 15529-15532. DOI
299) P. Tegeder, M. Marelli, M. Freitag, L. Polito, S. Lamping, R. Psaro, F. Glorius, B. J. Ravoo,* C. Evangelisti,*
Metal vapor synthesis of ultrasmall Pd nanoparticles functionalized with N-heterocyclic carbenes,
Dalton Trans. 2018, 47, 12647-12651. DOI
298) F. Strieth-Kalthoff, M. J. James, M. Teders, L. Pitzer, F. Glorius,
Energy transfer catalysis mediated by visible light: principles, applications, directions,
Chem. Soc. Rev. 2018, 47, 7190-7202. DOI
297) M. Teders, C. Henkel, L. Anhäuser, F. Strieth-Kalthoff, A. Goméz-Suárez, R. Kleinmans, A. Kahnt, A. Rentmeister, D. M. Guldi,* F. Glorius,*
The energy-transfer-enabled biocompatible disulfide–ene reaction,
Nat. Chem. 2018, 10, 981-988. DOI
Corresponding behind the paper blog entry in the Nature Research Community
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Highlighted by Phys.org; Chemie.de; Labo; LocalXXL; World University News; Research-in-Germany; Chemie-Link.
296) M. J. James, J. L. Schwarz, F. Strieth-Kalthoff, B. Wibbeling, F. Glorius,
Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer,
J. Am. Chem. Soc. 2018, 140, 8624-8628. DOI
295) W. Li, M. Wollenburg, F. Glorius,
Enantioselective synthesis of 2-oxazolidinones by ruthenium(II)–NHC-catalysed asymmetric hydrogenation of 2-oxazolones,
Chem. Sci. 2018, 9, 6260-6263. DOI
Highlighted in Synfacts 2018, 14, 1051.
294) D. T. Nguyen,§ M. Freitag,§ M. Körsgen, S. Lamping, A. Rühling, A. H. Schäfer, M. H. Siekman, H. F. Arlinghaus, W. G. van der Wiel, F. Glorius,* B. J. Ravoo,*
Versatile Micropatterns of N-Heterocyclic Carbenes on Gold Surfaces: Increased Thermal and Pattern Stability with Enhanced Conductivity,
Angew. Chem. Int. Ed. 2018, 57, 11465-11469; Angew. Chem. 2018, 130, 11637-11641. DOI
§ Both authors contributed equally.
293) S. Greßies, F. Klauck, J. H. Kim, C. Daniliuc, F. Glorius,
Ligand-Enabled Enantioselective Csp3-H Activation of Tetrahydroquinolines and Saturated Aza-Heterocycles by Rh(I),
Angew. Chem. Int. Ed. 2018, 57, 9950-9954; Angew. Chem. 2018, 130, 10098-10102. DOI
Highlighted by Angewandte Chemie as very important paper.
292) L. Rakers, L. M. Martínez-Prieto, A. M. López-Vinasco, K. Philippot, P. W. N. M. van Leeuwen, B. Chaudret,* F. Glorius,*
Ruthenium nanoparticles ligated by cholesterol-derived NHCs and their application in the hydrogenation of arenes,
Chem. Commun. 2018, 54, 7070-7073. DOI
Highlighted in Organic Chemistry Portal
291) M. P. Wiesenfeldt, T. Knecht, C. Schlepphorst, F. Glorius,
Silylarene hydrogenation - a strategic approach enabling direct access to versatile silylated saturated carbo- and heterocycles,
Angew. Chem. Int. Ed. 2018, 57, 8297-8300; Angew. Chem. 2018, 130, 8429-8432. DOI
290) S. Mukherjee, T. Patra, F. Glorius,
Cooperative Catalysis: A Strategy to Synthesize Trifluoromethyl-thioesters from Aldehydes,
ACS Catal. 2018, 8, 5842-5846. DOI
289) Q. Lu, S. Mondal, S. Cembellín, F. Glorius,
Mn(I)/Ag(I) Relay Catalysis: Traceless Diazo-Assisted C(sp2)–H/C(sp3)–H Coupling to β-(Hetero)Aryl/Alkenyl Ketones,
Angew. Chem. Int. Ed. 2018, 57, 10732-10736; Angew. Chem. 2018, 130, 10892-10896. DOI
288) R. A. Garza-Sanchez, T. Patra, A. Tlahuext-Aca, F. Strieth-Kalthoff, F. Glorius,
DMSO as switchable alkylating agent in heteroarene C–H functionalization,
Chem. Eur. J. 2018, 24, 10064-10068. DOI
287) L. Rakers, D. Grill, A. L. L. Matos, S. Wulff, D. Wang, J. Börgel, M. Körsgen, H. F. Arlinghaus, H.-J. Galla,* V. Gerke,* F. Glorius,*
Addressable Cholesterol Analogs for Live Imaging of Cellular Membranes,
Cell Chem. Biol. 2018, 25, 952-961.e12. DOI
Highlighted by WWU Münster
Highlighted by Cells in motion (Cluster of excellence)
Highlighted on MTA - Das Portal
Highlighted on PhysOrg
Highlighted by Science Trends
286) L. Rakers, F. Glorius,
Flexible design of ionic liquids for membrane interactions,
Biophys Rev. 2018, 10, 747-750. DOI
285) S. Singha, T. Patra, C. G. Daniliuc, F. Glorius,
Highly Enantioselective [5+2] Annulations through Cooperative NHC Organocatalysis and Palladium Catalysis,
J. Am. Chem. Soc. 2018, 140, 3551-3554. DOI
Highlighted in ChemistryViews
284) X. Wang, Y. Li, T. Knecht, C. G. Daniliuc, K. Houk,* F. Glorius,*
Unprecedented Dearomatized Spirocyclopropane in a Sequential Rh(III)-catalyzed C-H Activation and Rearrangement Reaction,
Angew. Chem. Int. Ed. 2018, 57, 5520-5524; Angew. Chem. 2018, 130, 5618-5622. DOI
283) A. Tlahuext-Aca, R. A. Garza-Sanchez, M. Schäfer, F. Glorius,
Visible-Light-Mediated Synthesis of Ketones by the Oxidative Alkylation of Styrenes,
Org. Lett. 2018, 20, 1546-1549. DOI
Highlighted in ChemistryViews
282) A. Lv, M. Freitag, K. M. Chepiga, A. H. Schäfer, F Glorius,* L. Chi,*
N-Heterocyclic Carbene-Treated Gold Surfaces in Pentacene Organic Field-Effect Transistors: Improved Stability and Contact at the Interface,
Angew. Chem. Int. Ed. 2018, 57, 4792-4796; Angew. Chem. 2018, 130, 4883-4887. DOI
281) M. Koy, F. Sandfort, A. Tlahuext-Aca, L. Quach, C. G. Daniliuc, F. Glorius,
Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light,
Chem. Eur. J. 2018, 24, 4552-4555. DOI
Paper was most accessed from 10/2018-09/2019.
280) A. Tlahuext-Aca, L. Candish, R. A. Garza-Sanchez, F. Glorius,
Decarboxylative Olefination of Activated Aliphatic Acids Enabled by Dual Organophotoredox/Copper Catalysis,
ACS Catal. 2018, 8, 1715-1719. DOI
279) X. Wang, A. Lerchen, C. G. Daniliuc, F. Glorius,
Efficient Synthesis of Arylated Furans Enabled by a Sequential Rh-catalyzed Arylation and Cycloisomerization of Cyclopropenes,
Angew. Chem. Int. Ed. 2018, 57, 1712-1716; Angew. Chem. 2018, 130, 1728-1732. DOI
278) T. Gensch, M. James, T. Dalton, F. Glorius,
Increasing Catalyst Efficiency in C−H Activation Catalysis,
Angew. Chem. Int. Ed. 2018, 57, 2296-2306; Angew. Chem. 2018, 130, 2318-2328. DOI
277) Q. Lu, S. Cembellín Santos, S. Greßies, S. Singha, C. Daniliuc, F. Glorius,
Manganese(I)-Catalyzed C-H (2-indolyl)methylation: Expedient Access to Diheteroarylmethanes,
Angew. Chem. Int. Ed. 2018, 57, 1399-1403; Angew. Chem. 2018, 130, 1413-1417. DOI
276) S. Vásquez-Céspedes, X. Wang, F. Glorius,
Plausible Rh(V) Intermediates in Catalytic C−H Activation Reactions,
ACS Catal. 2018, 8, 242-257. DOI
275) C. Zhu, J. L. Schwarz, S. Cembellín, S. Greßies, F. Glorius,
Highly Selective Manganese(I)/Lewis Acid Cocatalyzed Direct C−H Propargylation Using Bromoallenes,
Angew. Chem. Int. Ed. 2018, 57, 437-441; Angew. Chem. 2018, 130, 445-449. DOI
274) C. Schlepphorst, M. P. Wiesenfeldt, F. Glorius,
Enantioselective Hydrogenation of Imidazo[1,2-a]pyridines,
Chem. Eur. J. 2018, 24, 356-359. DOI
2017
273) S. Mukherjee, R. A. Garza-Sanchez§, A. Tlahuext-Aca§, F. Glorius,
Alkynylation of Csp2(O)–H Bonds Enabled by Photoredox-Mediated Hydrogen-Atom Transfer,
Angew. Chem. Int. Ed. 2017, 56, 14723-14726; Angew. Chem. 2017, 129, 14915-14919. DOI
§ Both authors contributed equally.
272) L. Pitzer§, F. Sandfort§, F. Strieth-Kalthoff, F. Glorius,
Intermolecular Radical Addition to Carbonyls Enabled by Visible Light Photoredox Initiated Hole Catalysis,
J. Am. Chem. Soc. 2017, 139, 13652-13655. DOI
§ Both authors contributed equally.
Highlighted in Synfacts 2017, 13, 1313.
271) S. Röser, A. Lerchen, L. Ibing, X. Cao, J. Kasnatscheew, F. Glorius,* M. Winter,* R. Wagner,*
Highly effective solid electrolyte interphase (SEI)-forming electrolyte additive enabling high voltage lithium ion batteries,
Chem. Mater. 2017, 29, 7733-7739. DOI
270) Q. Lu§, S. Greßies§, S. Cembellín, F. J. R. Klauck, C. G. Daniliuc, F. Glorius,
Redox-Neutral Manganese(I)-Catalyzed C–H Activation: Traceless Directing Group Enabled Regioselective Annulation,
Angew. Chem. Int. Ed. 2017, 56, 12778-12782; Angew. Chem. 2017, 129, 12954-12958. DOI
§ Both authors contributed equally.
269) T. Gensch§, M. Teders§, F. Glorius,
An Approach to Comparing the Functional Group Tolerance of Reactions,
J. Org. Chem. 2017, 82, 9154-9159. DOI
§ Both authors contributed equally.
Highlighted in Chemistry & Engineering News: T. Nguyen, Chem. Eng. News 2017, 95 (38), 16-18; What’s the best way to show a new chemical reaction’s scope?
268) M. P. Wiesenfeldt, Z. Nairoukh, W. Li, F. Glorius,
Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes,
Science 2017, 357, 908-912. DOIHighlighted in Chemistry World;
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Highlighted in Synfacts 2017, 13, 1265.
267) F. J. R. Klauck§, M. J. James§, F. Glorius,
Deaminative Strategy for the Visible Light-Mediated Generation of Alkyl Radicals,
Angew. Chem. Int. Ed. 2017, 56, 12336-12339; Angew. Chem. 2017, 129, 12505-12509. DOI
§ Both authors contributed equally.
266) M. Fleige, F. Glorius,
α-Unsubstituted Pyrroles by NHC-Catalyzed Three-Component Coupling - Direct Synthesis of a Versatile Atorvastatin Derivative,
Chem. Eur. J. 2017, 23, 10773-10776. DOI
Highlighted in Synfacts 2017, 13, 1117.
265) F. Lied, T. Patra, F. Glorius,
Group 9 Transition Metal-Catalyzed C-H Halogenations,
Isr. J. Chem. 2017, 57, 945-952. DOI
264) J. B. Ernst, C. Schwermann, G.-I. Yokota, M. Tada, S. Muratsugu,* N. L. Doltsinis,* F. Glorius,*
Molecular Adsorbates Switch on Heterogeneous Catalysis: Induction of Reactivity by N-Heterocyclic Carbenes,
J. Am. Chem. Soc. 2017, 139, 9144-9147. DOI
263) D. Janssen-Müller, C. Schlepphorst, F. Glorius,
Privileged Chiral N-Heterocyclic Carbene Ligands for Asymmetric Transition-Metal Catalysis,
Chem. Soc. Rev. 2017, 46, 4845-4854. DOI
262) A. Lerchen, T. Knecht, M. Koy, C. G. Daniliuc, F. Glorius,
A General Cp*Co(III)-Catalyzed Intramolecular C–H Activation Approach for the Efficient Total Syntheses of Aromathecin, Protoberberine and Tylophora Alkaloids,
Chem. Eur. J. 2017, 23, 12149-12152. DOI
261) L. M. Martínez-Prieto, L. Rakers, Á. M. López-Vinasco, I. Cano, Y. Coppel, K. Philippot, F. Glorius,* B. Chaudret,* P. W. N. M. van Leeuwen,*
Soluble Platinum Nanoparticles ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts,
Chem. Eur. J. 2017, 23, 12779-12786. DOI
260) L. Candish, M. Teders, F. Glorius,
Transition-Metal-Free, Visible-Light-Enabled Decarboxylative Borylation of Aryl N‑Hydroxyphthalimide Esters,
J. Am. Chem. Soc. 2017, 139, 7440-7443. DOI
Highlighted in Organic Chemistry Portal
259) R. A. Garza-Sanchez, A. Tlahuext-Aca, G. Tavakoli, F. Glorius,
Visible-Light-Mediated Direct Decarboxylative C−H Functionalization of Heteroarenes,
ACS Catal. 2017, 7, 4057-4061. DOIPlease, also see our
Correction to “Visible Light-Mediated Direct Decarboxylative C−H 2 Functionalization of Heteroarenes”,
ACS Catal. 2022, 12, 6640. DOI
258) M. Teders, L. Pitzer, S. Buss, F. Glorius,
Regioselective Synthesis of 2‑Substituted Indoles from Benzotriazoles and Alkynes by Photoinitiated Denitrogenation,
ACS Catal. 2017, 7, 4053-4056. DOI
257) X. Wang, T. Gensch, A. Lerchen, C. G. Daniliuc, F. Glorius,
Cp*Rh(III)/Bicyclic Olefin Cocatalyzed C−H Bond Amidation by Intramolecular Amide Transfer,
J. Am. Chem. Soc. 2017, 139, 6506-6512. DOI
256) C. Kutzscher, D. Janssen-Müller, A. Notzon, U. Stoeck, V. Bon, I. Senkovska, S. Kaskel*, F. Glorius*,
Synthesis of the homochiral metal-organic framework DUT-129 based on a chiral dicarboxylate linker with 6 stereocenters,
CrystEngComm. 2017, 19, 2494-2499. DOI
255) Q. Lu, S. Greßies, F. J. R. Klauck, F. Glorius,
Manganese(I)-Catalyzed Regioselective C–H Allenylation: Direct Access to 2-Allenylindoles,
Angew. Chem. Int. Ed. 2017, 56, 6660-6664; Angew. Chem. 2017, 129, 6760-6764. DOI
254) S. Vásquez-Céspedes, M. Holtkamp, U. Karst,* F. Glorius,*
Reusable and magnetic Palladium and Copper Oxide catalysts in direct ortho- and meta-arylation of anilide derivatives,
Synlett 2017, 28, 2759-2754. DOI
Highlighted as Synfacts of the month in Synfacts 2018, 14, 0315.
253) C. Guo,* D. Janssen-Müller, M. Fleige, A. Lerchen, C. G. Daniliuc, F. Glorius,*
Mechanistic Studies on a Cooperative NHC Organocatalysis/Palladium Catalysis System: Uncovering Significant Lessons for Mixed Chiral Pd(NHC)(PR3) Catalyst Design,
J. Am. Chem. Soc. 2017, 139, 4443-4451. DOI
252) L. Candish, M. Freitag, T. Gensch, F. Glorius,
Mild, visible light-mediated decarboxylation of aryl carboxylic acids to access aryl radicals,
Chem. Sci. 2017, 8, 3618-3622. DOI
251) Q. Lu, F. J. R. Klauck, F. Glorius,
Manganese-Catalyzed Allylation via Sequential C–H and C–C/C–Het Bond Activation,
Chem. Sci. 2017, 8, 3379-3383. DOI
250) N. Möller§, A. Rühling§, S. Lamping, T. Hellwig, C. Fallnich, B. J. Ravoo,* F. Glorius,*
Stabilization of High Oxidation State Upconversion Nanoparticles by N-Heterocyclic Carbenes (NHCs),
Angew. Chem. Int. Ed. 2017, 56, 4356-4360; Angew. Chem. 2017, 129, 4421-4425. DOI
§ Both authors contributed equally.
249) D. Paul, F. Heins, S. Krupski, A. Hepp, C. G. Daniliuc, K. Klahr, J. Neugebauer, F. Glorius,* F. E. Hahn,*
Synthesis and Reactivity of Intramolecularly NHC-Stabilized Germylenes and Stannylenes,
Organometallics 2017, 36, 1001-1008. DOI
248) W. Li, M. Wiesenfeldt, F. Glorius,
Ruthenium−NHC−Diamine Catalyzed Enantioselective Hydrogenation of Isocoumarins,
J. Am. Chem. Soc. 2017, 139, 2585-2588. DOI
Highlighted in Synfacts 2017, 13, 0494.
247) A. Tlahuext-Aca, R. A. Garza-Sanchez, F. Glorius,
Multicomponent Oxyalkylation of Styrenes Enabled by Hydrogen Bond Assisted Photoinduced Electron Transfer,
Angew. Chem. Int. Ed. 2017, 56, 3708-3711; Angew. Chem. 2017,129, 3762-3765. DOI
246) L. Rakers, L. Tebben,* F. Glorius*,
co.labore – A Genuine Collaboration between Arts and Science, Reflecting Viewpoints and Merging Skills,
Chem. Eur. J. 2017, 23, 5860-5863. DOI
Publication is part of special issue of CEJ for the SFB 858 on “Synergetic effects in Chemistry”.
245) D. Janssen-Müller,§ S. Singha,§ F. Lied, K. Gottschalk, F. Glorius,
NHC-Organocatalyzed CAr–O Bond Cleavage: Mild access to 2 Hydroxybenzophenones,
Angew. Chem. Int. Ed. 2017, 56, 6276-6279; Angew. Chem. 2017, 129, 6373-6376. DOI
§ Both authors contributed equally.
Highlighted in Synfacts 2017, 13, 0651.
244) F. Lied, H. Brodnik Žugelj, S. Kress, B. Štefane, F. Glorius*, M. Lautens*,
Employing Pd-Catalyzed C–H Arylation in Multicomponent-Multicatalyst Reactions (MC)2R: One-Pot Synthesis of Dihydrobenzoquinolines,
ACS Catal. 2017, 7, 1378-1382. DOI
243) J. Zhang, C. Chang, B. Yang, N. Cao, C. Peng, H. Zhang, D.-T. D. Tang, F. Glorius, G. Erker, H. Fuchs, Q. Li,* L. Chi,*
Step Edge Assisted Direct Linear Alkane Coupling,
Chem. Eur. J. 2017, 23, 6185-6189. DOI
Publication is part of special issue of CEJ for the SFB 858 on “Synergetic effects in Chemistry”.
242) P. Drücker, A. Rühling, D. Grill, D. Wang, A. Draeger, V. Gerke, F. Glorius,* H.-J. Galla,*
Imidazolium Salts Mimicking the Structure of Natural Lipids Exploit Remarkable Properties Forming Lamellar Phases and Giant Vesicles,
Langmuir 2017, 33, 1333-1342. DOI
This paper was selected for the Langmuir front cover image of the issue it appears in.
241) A. Rühling, D. Wang, J. B. Ernst, S. Wulff, R. Honeker, C. Richter, A. Ferry, H.-J. Galla,* F. Glorius,*
Influence of the Headgroup of Azolium-Based Lipids on Their Biophysical Properties and Cytotoxicity,
Chem. Eur. J. 2017, 23, 5920-5924. DOI
Publication is part of special issue of CEJ for the SFB 858 on “Synergetic effects in Chemistry”; selected for an Inside Cover.
240) A. Rühling§, L. Rakers§, F. Glorius,
Long alkyl chain NHC palladium complexes for the amination and hydrodehalogenation of aryl chlorides in lipophilic media,
ChemCatChem 2017, 9, 547-550. DOI
§ Both authors contributed equally.
Publication is part of special issue celebrating the 50th Annual Catalysis Meeting in Weimar; selected for an Inside Cover.
239) X. Wang, A. Lerchen, T. Gensch, T. Knecht, C. G. Daniliuc, F. Glorius,
Combination of Cp*RhIII-Catalyzed C-H Activation and a Wagner–Meerwein-Type Rearrangement,
Angew. Chem. Int. Ed. 2017, 56, 1381-1384; Angew. Chem. 2017, 129, 1401-1405. DOI
238) M. Teders, A. Gómez-Suárez§, L. Pitzer§, M. N. Hopkinson, F. Glorius,
Diverse Visible-Light-Promoted Functionalizations of Benzotriazoles Inspired by Mechanism-Based Luminescence Screening,
Angew. Chem. Int. Ed. 2017, 56, 902-906; Angew. Chem. 2017, 129, 921-925. DOI
§ Both authors contributed equally.
237) G. Wang, A. Rühling, S. Amirjalayer, M. Knor, J. B. Ernst, C. Richter, H.-J. Gao, A. Timmer, H.-Y. Gao, N. L. Doltsinis, F. Glorius,* H. Fuchs,*
Ballbot-type motion of N-heterocyclic carbenes on gold surfaces,
Nature Chem. 2017, 9, 152-156. DOI
Highlighted in Chemistry World
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236) Q. Lu, F. Glorius,
Radical Enantioselective C(sp3)-H Functionalization,
Angew. Chem. Int. Ed. 2017, 56, 49-51; Angew. Chem. 2017, 129, 49-51. DOI
235) J. B. Ernst, L. Rakers, F. Glorius,
Sodium Chloride Catalyzed Regioselective Trifluoromethylthiolation of Furans,
Synthesis 2017, 49, 260-268. DOI
Publication is part of a special issue dedicated to Prof. Dieter Enders.
2016
234) S. Mukherjee,§ B. Maji,§ A. Tlahuext-Aca, F. Glorius,
Visible-Light-Promoted Activation of Unactivated C(sp3)−H Bonds and Their Selective Trifluoromethylthiolation,
J. Am. Chem. Soc. 2016, 138, 16200-16203. DOI
§ Both authors contributed equally.
233) D. Wang, D. H. de Jong, A. Rühling, V. Lesch, K. Shimizu, S. Wulff, A. Heuer,* F. Glorius,* H.-J. Galla,*
Imidazolium-Based Lipid Analogues and Their Interaction with Phosphatidylcholine Membranes,
Langmuir 2016, 32, 12579–12592. DOI
232) L. Rakers, L. Tebben, F. Glorius,
Perspektivwechsel,
Nachrichten aus der Chemie 2016, 64, 1188-1189. DOI
231) F. Lied, A. Lerchen, T. Knecht, C. Mück-Lichtenfeld, F. Glorius,
Versatile Cp*Rh(III)-Catalyzed Selective ortho-Chlorination of Arenes and Heteroarenes,
ACS Catal. 2016, 6, 7839-7843. DOI
230) J. H. Kim, S. Greßies, M. Boultadakis-Arapinis, C. Daniliuc, F. Glorius,
Rh(I)/NHC*-Catalyzed Site- and Enantioselective Functionalization of C(sp3)–H Bonds Toward Chiral Triarylmethanes,
ACS Catal. 2016, 6, 7652-7656. DOI
Highlighted in Synfacts 2017, 13, 0061.
229) A. Lerchen, T. Knecht, C. G. Daniliuc, F. Glorius,
Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes,
Angew. Chem. Int. Ed. 2016, 55, 15166-15170; Angew. Chem. 2016, 128, 15391-15395. DOI
228) D. Paul, B. Beiring, M. Plois, N. Ortega, S. Kock, D. Schlüns, J. Neugebauer,* R. Wolf,* F. Glorius,*
A Cyclometalated Ruthenium-NHC Precatalyst for the Asymmetric Hydrogenation of (Hetero)arenes and Its Activation Pathway,
Organometallics 2016, 35, 3641-3646. DOI
227) X. Wang, T. Gensch, F. Glorius,
Highly selective synthesis of 6-substituted benzothiophenes by Sc(OTf)3-catalyzed intermolecular cyclization and sulfur migration,
Org. Chem. Front. 2016, 3, 1619-1623. DOI
226) M. N. Hopkinson, A. Tlahuext-Aca, F. Glorius,
Merging Visible Light Photoredox and Gold Catalysis,
Acc. Chem. Res. 2016, 49, 2261-2272. DOI
Published as part of the Accounts of Chemical Research special issue “Photoredox Catalysis in Organic Chemistry”
225) J. B. Ernst, S. Muratsugu,* F. Wang, M. Tada, F. Glorius,*
Tunable Heterogeneous Catalysis – N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts to Tune Reactivity and Selectivity,
J. Am. Chem. Soc. 2016, 138, 10718-10721. DOI
224) D. Janssen-Müller, S. Singha, T. Olyschläger, C. G. Daniliuc, F. Glorius,
Annulation of o-Quinodimethanes (o-QDM) through NHC-Catalysis for the Synthesis of 1-Isochromanones,
Org. Lett. 2016, 18, 4444-4447. DOI
Highlighted in Synfacts 2016, 12, 1125. DOI
223) D. Zhao, L. Candish, D. Paul, F. Glorius,
N-Heterocyclic carbenes in asymmetric hydrogenation,
ACS Catal. 2016,6, 5978-5988. DOI
222) S. Vásquez-Céspedes, K. M. Chepiga, N. Möller, A. H. Schäfer, F. Glorius,
Direct C–H Arylation of Heteroarenes with Copper Impregnated on Magnetite as a Reusable Catalyst: Evidence for CuO Nanoparticle Catalysis in Solution,
ACS Catal. 2016, 6, 5954-5961. DOI
221) D. Janssen-Müller, M. Fleige, D. Schlüns, M. Wollenburg, C. G. Daniliuc, J. Neugebauer,* F. Glorius,*
NHC-Catalyzed Enantioselective Dearomatizing Hydroacylation of Benzofurans and Benzothiophenes for the Synthesis of Spirocycles,
ACS Catal. 2016, 6, 5735-5739. DOI
220) M. Fleige,§ J. Möbus,§ T. vom Stein, F. Glorius, D. W. Stephan,*
Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane,
Chem. Commun. 2016, 52, 10830-10833. DOI
§ Both authors contributed equally.
219) A. Tlahuext-Aca, M. N. Hopkinson, C. G. Daniliuc, F. Glorius,
Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse (C,N)-Cyclometalated Gold(III) Complexes,
Chem. Eur. J. 2016, 22, 11587-11592. DOI
Highlighted as very important paper;
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218) T. Gensch,§ F. J. R. Klauck,§ F. Glorius,
Cobalt-Catalyzed C−H Thiolation through Dehydrogenative Cross-Coupling,
Angew. Chem. Int. Ed. 2016, 55, 11287-11291; Angew. Chem. 2016, 128, 11457-11461. DOI
§ Both authors contributed equally.
217) C. Guo, M. Fleige, D. Janssen-Müller, C. G. Daniliuc, F. Glorius,
Cooperative N-Heterocyclic Carbene/Palladium-Catalyzed Enantioselective Umpolung Annulations,
J. Am. Chem. Soc. 2016, 138, 7840-7843. DOI
216) C. Schlepphorst, B. Maji, F. Glorius,
Ruthenium-NHC Catalyzed α-Alkylation of Methylene Ketones Provides Branched Products through Borrowing Hydrogen Strategy,
ACS Catal. 2016, 6, 4184-4188. DOI
215) L. Candish, E. A. Standley, A. Gómez-Suárez, S. Mukherjee, F. Glorius,
Catalytic Access to Alkyl Bromides, Chlorides and Iodides via Visible Light-Promoted Decarboxylative Halogenation,
Chem. Eur. J. 2016, 22, 9971-9974. DOI
214) T. Gensch, F. Glorius,
The straight dope on the scope of chemical reactions,
Science 2016, 352, 294-295. DOI
213) T. Gensch, M. N. Hopkinson, F. Glorius,* J. Wencel-Delord,*
Mild metal-catalyzed C–H activation: examples and concepts,
Chem. Soc. Rev. 2016, 45, 2900-2936. DOI
212) X. Wang, A. Lerchen, F. Glorius,
A Comparative Investigation: Group 9 Cp*M(III)-catalyzed Formal [4+2] Cycloaddition as an Atom-economic Approach to Quinazolines,
Org. Lett. 2016, 18, 2090-2093. DOI
211) P. Lara,* L. M. Martínez-Prieto,* M. Roselló-Merino, C. Richter, F. Glorius, S. Conejero, K. Philippot, B. Chaudret, NHC-stabilized Ru nanoparticles: Synthesis and surface studies,
Nano-Structures & Nano-Objects 2016, 6, 39-45. DOI
210) J. H. Kim, S. Greßies, F. Glorius,
Cooperative Lewis Acid/ Cp*Co(III)-Catalyzed C–H Bond Activation for the Synthesis of Isoquinolin-3-ones,
Angew. Chem. Int. Ed. 2016, 55, 5577-5581; Angew. Chem. 2016, 128, 5667-5671. DOI
209) A. Rühling, K. Schaepe, L. Rakers, B. Vonhören, P. Tegeder, B. J. Ravoo,* F. Glorius,*
Modular and bidentate hybrid NHC-thioether ligands for the stabilization of palladium nanoparticles in various solvents,
Angew. Chem. Int. Ed. 2016, 55, 5856-5860; Angew. Chem. 2016, 128, 5950-5955. DOI
208) M. N. Hopkinson, A. Gomez-Suarez, M. Teders, B. Sahoo, F. Glorius,
Accelerated Discovery in Photocatalysis using a Mechanism-Based Screening Method,
Angew. Chem. Int. Ed. 2016, 55, 4361-4366; Angew. Chem. 2016, 128, 4434-4439. DOI
This paper was selected for the Angewandte front cover image of the issue it appears in. Please, enjoy this "Catalyst Speed Dating"!
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207) Q. Lu, S. Vásquez-Céspedes, T. Gensch, F. Glorius,
Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles,
ACS Catal. 2016, 6, 2352-2356. DOI
206) A. Tlahuext-Aca, M. N. Hopkinson,§ R. A. Garza-Sanchez,§ F. Glorius,
Alkyne Difunctionalization by Dual Gold/Photoredox Catalysis,
Chem. Eur. J. 2016, 22, 5909-5913. DOI
§ Both authors contributed equally.
205) L. M. Martínez-Prieto,§ A. Ferry,§ L. Rakers, C. Richter, P. Lecante, K. Philippot,* B. Chaudret,* F. Glorius,*
Long-Chain NHC-stabilized RuNPs as Versatile Catalysts for One-pot Oxidation/Hydrogenation Reactions,
Chem. Commun. 2016, 52, 4768-4771. DOI
204) L. Candish,§ L. Pitzer,§ A. Gomez-Suarez, F. Glorius,
Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids,
Chem. Eur. J. 2016, 22, 4753-4756. DOI
§ Both authors contributed equally.
203) J. B. Ernst, A. Rühling, B. Wibbeling, F. Glorius,
Trichloromethylthiolation of N Heterocycles - Practical and Completely Regioselective,
Chem. Eur. J. 2016, 22, 4400-4404. DOI
202) R. Honeker, R. A. Garza-Sanchez, M. N. Hopkinson,* F. Glorius,*
Visible Light-Promoted Trifluoromethylthiolation of Styrenes via Dual Photoredox/Halide Catalysis,
Chem. Eur. J. 2016, 22, 4395-4399. DOI
Selected as hot paper by Chemistry - A European Journal;
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201) W. Li, C. Schlepphorst, C. Daniliuc, F. Glorius,
Asymmetric Hydrogenation of Vinylthioethers: Access to Optically Active 1,5-Benzothiazepine Derivatives,
Angew. Chem. Int. Ed. 2016, 55, 3300-3303; Angew. Chem. 2016, 128, 3361-3364. DOI
200) A. Lerchen, S. Vásquez-Céspedes, F. Glorius,
Cobalt(III)-catalyzed redox-neutral synthesis of unprotected indoles featuring an N–N bond cleavage,
Angew. Chem. Int. Ed. 2016, 55, 3208-3211; Angew. Chem. 2016, 128, 3261-3265. DOI
199) A. Tlahuext-Aca§, M. N. Hopkinson§, B. Sahoo, F. Glorius,
Dual Gold/Photoredox-Catalyzed C(sp)−H Arylation of Terminal Alkynes with Diazonium Salts,
Chem. Sci. 2016, 7, 89-93. DOI
§ Both authors contributed equally.
2015
198) D. Wang, C. Richter, A. Rühling, S. Hüwel, F. Glorius,* H.-J. Galla,*
Anti-tumor activity and cytotoxicity in Vitro of novel 4,5-dialkylimidazolium surfactants,
Biochem. Biophys. Res. Commun. 2015, 467, 1033-1038. DOI
197) B. Sahoo§, M. N. Hopkinson§, F. Glorius,
External-Photocatalyst-Free Visible-Light-Mediated Synthesis of Indolizines,
Angew. Chem. Int. Ed. 2015, 54, 15545-15549; Angew. Chem. 2015, 127, 15766-15770. DOI
§ Both authors contributed equally.
196) J. Wencel-Delord,* F. W. Patureau and F. Glorius,
Rh(III) and Ir(III) catalyzed C-C bond cross couplings from C-H bonds,
Top. Organomet. Chem. 2015, 55, 1-27. DOI
195) L. M. Martínez-Prieto, A. Ferry, P. Lara, C. Richter, K. Philippot,* F. Glorius,* B. Chaudret,*
New Route to Stabilize Ruthenium Nanoparticles with Non-Isolable Chiral N-Heterocyclic Carbenes,
Chem. Eur. J. 2015, 21, 17495-17502. DOI
194) A. Ferry,§ K. Schaepe,§ P. Tegeder, C. Richter, K. M. Chepiga, B. J. Ravoo,* F. Glorius,*
Negatively Charged N-Heterocyclic Carbene-Stabilized Pd and Au Nanoparticles and Efficient Catalysis in Water,
ACS Catal. 2015, 5, 5414-5420. DOI
§ Both authors contributed equally.
193) D. Wang,§ C. Richter,§ A. Rühling, P. Drücker, D. Siegmund, N. Metzler-Nolte, F. Glorius,* H.-J. Galla,*
A remarkably simple class of imidazolium-based lipids and their biological properties,
Chem. Eur J. 2015, 21, 15123-15126. DOI
§ Both authors contributed equally.
192) C. Guo, M. Fleige, D. Janssen-Müller, C. G. Daniliuc, F. Glorius,
Switchable selectivity in an NHC-catalysed dearomatizing annulation reaction,
Nature Chem. 2015, 7, 842-847. DOI
191) J. H. Kim, T. Gensch, D. Zhao, L. Stegemann, C. A. Strassert,* F. Glorius,*
Rh(III)-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection,
Angew. Chem. Int. Ed. 2015, 54, 10975–10979; Angew. Chem. 2015, 127, 11126–11130. DOI
190) A. Rühling, H.-J. Galla, F. Glorius,
A Remarkably Simple Hybrid Surfactant–NHC Ligand, Its Gold-Complex, and Application in Micellar Catalysis,
Chem. Eur. J. 2015, 21, 12291-12294. DOI
189) T. Gensch,§ S. Vásquez-Céspedes,§ D.-G. Yu, F. Glorius,
Cobalt(III)-Catalyzed Directed C−H Allylation,
Org. Lett. 2015, 17, 3714-3717. DOI
§ Both authors contributed equally.
188) X. Wang,§ D.-G. Yu,§ F. Glorius,
Cp*Rh(III)-Catalyzed Arylation of sp3 C−H Bonds,
Angew. Chem. Int. Ed. 2015, 54, 10280-10283;Angew. Chem. 2015, 127, 10419-10422. DOI
§ Both authors contributed equally.
187) B. Sahoo, J.-L. Li, and F. Glorius,
Visible Light Photoredox Catalyzed Semipinacol-Type Rearrangement: Trifluoromethylation/Ring Expansion via a Radical-Polar Mechanism,
Angew. Chem. Int. Ed. 2015, 54, 11577-11580; Angew. Chem. 2015, 127, 11740-11744. DOI
186) J. Wysocki, C. Schlepphorst, F. Glorius,
Asymmetric Homogeneous Hydrogenation of 2-Pyridones,
Synlett 2015, 26, 1557-1562. DOI
Selected for Synlett Best Paper Award 2015
185) S. Helten, B. Sahoo, P. Müller, D. Janßen-Müller, N. Klein, R. Grünker, V. Bon, F. Glorius, S. Kaskel, I. Senkovska,*
Functional group tolerance in BTB-based metal–organic frameworks (BTB – benzene-1,3,5-tribenzoate),
Microporous Mesoporous Mater. 2015, 216, 42-50. DOI
184) R. Honeker§, J. B. Ernst§, F. Glorius,
Transition Metal free Trifluoromethylthiolation of N-Heteroarenes,
Chem. Eur. J. 2015, 21, 8047-8051. DOI
§ Both authors contributed equally.
Highlighted in Org. Process Res. Dev. 2016, 20, 707-717.
183) D. Janssen-Müller, M. Schedler, M. Fleige, C. G. Daniliuc, F. Glorius,
Enantioselective Intramolecular Hydroacylation of Unactivated Alkenes: An NHC-Catalyzed Robust and Versatile Formation of Cyclic Chiral Ketones,
Angew. Chem. Int. Ed. 2015, 54, 12492-12496; Angew. Chem. 2015, 127, 12671-12675. DOI
Highlighted in Synfacts 2015, 11, 0659 as Synfact of the month.
182) S. Vásquez-Céspedes§, A. Ferry§, L. Candish, F. Glorius,
Heterogeneously Catalyzed Direct C-H Thiolation of Heteroarenes,
Angew. Chem. Int. Ed. 2015, 54, 5772-5776; Angew. Chem. 2015, 127, 5864-5868. DOI
§ Both authors contributed equally.
Selected as hot paper by Angewandte Chemie.
181) E.-C. Fritz, C. Nimphius, A. Goez, S. Würtz, M. Peterlechner, J. Neugebauer, F. Glorius,* B. J. Ravoo,*
Sequential Surface Modification of Au Nanoparticles: From Surface-Bound AgI Complexes to Ag0 Doping,
Chem. Eur. J. 2015, 21, 4541-4545. DOI
180) K. D. Collins,* F. Glorius,*
Intermolecular Reaction Screening as a Tool for Reaction Evaluation,
Acc. Chem. Res. 2015, 48, 619-627. DOI
(invited for a special edition on “Synthesis, Design and Molecular Function” edited by Paul A. Wender)
179) N. Schröder, F. Lied, F. Glorius,
Dual role of Rh(III)-catalyst enables regioselective halogenation of (electron-rich) heterocycles,
J. Am. Chem. Soc. 2015, 137, 1448-1451. DOI
Highlighted in Synfacts 2015, 11, 0366 as Synfact of the month.
178) D. Zhao*§, J. H. Kim§, L. Stegemann, C. A. Strassert, F. Glorius,*
Cobalt(III)-Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems,
Angew. Chem. Int. Ed. 2015, 54, 4508-4511; Angew. Chem. 2015, 127, 4591-4594. DOI
§ Both authors contributed equally.
177) K. D. Collins, R. Honeker§, S. Vásquez-Céspedes§, D.-T. D. Tang, F. Glorius,
C–H Arylation of Triphenylene, Naphthalene and Related Arenes using Pd/C,
Chem. Sci. 2015, 6, 1816-1824. DOI
§ Both authors contributed equally.
176) D. Zhao,§ S. Vásquez-Céspedes,§ F. Glorius,
Rhodium(III)-Catalyzed Cyclative Capture Approach to Diverse 1-Aminoindoline Derivatives at Room Temperature,
Angew. Chem. Int. Ed. 2015, 54, 1657-1661; Angew. Chem. 2015, 127, 1677-1681. DOI
§ Both authors contributed equally.
175) S. Helten§, B. Sahoo§, V. Bon, I. Senkovska, S. Kaskel,* F. Glorius,*
Copolymerisation at work: the first example of a highly porous MOF comprising a triarylborane-based linker,
CrystEngComm 2015, 17, 307-312. DOI
§ Both authors contributed equally.
2014
174) D.-G. Yu, T. Gensch, F. de Azambuja, S. Vásquez-Céspedes, F. Glorius,
Co(III)-Catalyzed C–H Activation/Formal SN-type Reactions: Selective and Efficient Cyanation, Halogenation and Allylation,
J. Am. Chem. Soc. 2014, 136, 17722-17725. DOI
173) C. Guo, B. Sahoo, C. G. Daniliuc, F. Glorius,
N-Heterocyclic Carbene Catalyzed Switchable Reactions of Enals with Azoalkenes: Formal [4+3] and [4+1] Annulations for the Synthesis of 1,2-Diazepines and Pyrazoles,
J. Am. Chem. Soc. 2014, 136, 17402-17405. DOI
Highlighted in Chem. & Eng. News 2014, 92, issue 49, p. 30. LINK
Highlighted in JACS Spotlights. LINK
172) M. N. Hopkinson, B. Sahoo, F. Glorius,
Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes,
Adv. Synth. Catal. 2014, 356, 2794-2800. DOI
171) K. D. Collins, T. Gensch, F. Glorius,
Contemporary screening approaches to reaction discovery and development,
Nat. Chem. 2014, 6, 859–871. DOI
170) J.-L. Li, B. Sahoo, C.-G. Daniliuc, F. Glorius,
Conjugate Umpolung of β,β-Disubstituted Enals by Dual Catalysis with an N-Heterocyclic Carbene and a Brønsted Acid: Facile Construction of Contiguous Quaternary Stereocenters,
Angew. Chem. Int. Ed. 2014, 53, 10515-10519; Angew. Chem. 2014, 126, 10683-10687. DOI
169) C. Guo, M. Schedler, C. G. Daniliuc, F. Glorius,
N-Heterocyclic Carbene Catalyzed Formal [3+2] Annulation Reaction of Enals: An Efficient Enantioselective Access to Spiro-Heterocycles,
Angew. Chem. Int. Ed. 2014, 53, 10232-10236; Angew. Chem. 2014, 126, 10397-10401. DOI
Highlighted in Synfacts 2014, 10, 1207.
168) M. N. Hopkinson, C. Richter, M. Schedler, F. Glorius,
An Overview of N-Heterocyclic Carbenes,
Nature 2014, 510, 485-496. DOI
167) D.-G. Yu, F. de Azambuja, T. Gensch, C. G. Daniliuc, F. Glorius,
The C-H Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse bis-Heterocycles via RhIII-Catalysis,
Angew. Chem. Int. Ed. 2014, 53, 9650-9654; Angew. Chem. 2014, 126, 9804-9809. DOI
Highlighted in Synfacts 2014, 10, 1023.
166) D.-G. Yu, F. de Azambuja, F. Glorius,
Direct Functionalization with Complete and Switchable Positional Control: Free Phenol as A Role Model,
Angew. Chem. Int. Ed. 2014, 53, 7710-7712; Angew. Chem. 2014, 126, 7842-7845. DOI
165) M. Schedler, N. E. Wurz, C. G. Daniliuc, F. Glorius,
N-Heterocyclic Carbene Catalyzed Umpolung of Styrenes: Mechanistic Elucidation and Selective Tail-to-Tail Dimerization,
Org. Lett. 2014, 16, 3134-3137. DOI
164) M. Suri, F. Glorius,
Synthesis of Tetrasubstituted 1H-Pyrazoles by Copper-mediated Coupling of Enaminones with Nitriles,
Org. Synth. 2014, 91, 211-220.
163) K. D. Collins, F. Lied, F. Glorius,
Preparation of Conjugated 1,3-Enynes using Rh(III) Catalysed Alkynylation of Alkenes via C-H activation,
Chem. Commun. 2014, 50, 4459-4461. DOI
162) N. Kuhl, N. Schröder, F. Glorius,
Formal SN-type reactions in Rh(III)-catalyzed C–H bond activation,
Adv. Synth. Catal. 2014, 356, 1443-1460. DOI
161) D. Zhao, F. Lied, F. Glorius,
Rh(III)-Catalyzed C-H Functionalization/Aromatization Cascade with 1,3-Dienes: A Redox-Neutral and Regioselective Access to Isoquinolines, Chem. Sci. 2014, 5, 2869-2873. DOI
160) M. Boultadakis-Arapinis, M. N. Hopkinson, F. Glorius,
Using Rh(III)-Catalyzed C–H Activation as a Tool for the Selective Functionalization of Ketone-Containing Molecules,
Org. Lett. 2014, 16, 1630-1633. DOI>
159) J. Wysocki, N. Ortega, F. Glorius,
Asymmetric Hydrogenation of Disubstituted Furans,
Angew. Chem. Int. Ed. 2014, 53, 8751-8755; Angew. Chem. 2014, 126, 8896-8900. DOI
Highlighted in Synfacts 2014, 10, 0949.
158) C. Richter§, K. Schaepe§, F. Glorius,* B. J. Ravoo,*
Tailor-made N-Heterocyclic Carbenes for Nanoparticle Stabilization,
Chem. Commun. 2014, 50, 3204-3207. DOI
§ Both authors contributed equally.
157) K. D. Collins, A. Rühling, F. Glorius,
Application of a Robustness Screen for the evaluation of synthetic organic methodology,
Nat. Protoc. 2014, 9, 1348-1353. DOI
156) M. N. Hopkinson§, B. Sahoo§, J.-L. Li, F. Glorius,
Dual Catalysis sees the Light: Combining Photoredox with Organo-, Acid and Transition Metal Catalysis,
Chem. Eur. J. 2014, 20, 3874-3886. DOI
§ Both authors contributed equally.
155) D.-G. Yu, F. de Azambuja, F. Glorius,
α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed C–H Activation for the Synthesis of N-Heterocycles,
Angew. Chem. Int. Ed. 2014, 53, 2754-2758. DOI
Highlighted in Synfacts 2014, 10, 567.
154) Z. Shi, M. Boultadakis-Arapinis, D. C. Koester, F. Glorius,
Rh(III)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C–H activation,
Chem. Commun. 2014, 50, 2650-2652. DOI
153) D.-T. D. Tang, K. D. Collins, J. B. Ernst, F. Glorius,
Pd/C as a Catalyst for Completely Regioselective C-H Functionalization of Thiophenes under Mild Conditions,
Angew. Chem. Int. Ed. 2014, 53, 1809-1813; Angew. Chem. 2014, 126, 1840-1844. DOI
Highlighted in Synfacts 2014, 10, 0367.
152) K. D. Collins,* A. Rühling, F. Lied, F. Glorius,*
Rapid Assessment of Protecting Group Stability Using a Robustness Screen,
Chem. Eur. J. 2014, 20, 3800-3805. DOI
2013
151) T. Dröge, F. Glorius,
(1S,1"S,2S,2"S,5R,5"R )-5,5"-Dimethyl-2,2" -bis(1-methylethyl)-dispiro[cyclohexane-1,3'(2'H)-imidazo[5,1-b:4,3-b']bisoxazol[4]ium-7'(8' H),1"-cyclohexane]1,1,1-trifluoromethanesulfonate,
Encyclopedia of Reagents for Organic Synthesis (e-Eros) 2013. DOI
150) D. Zhao, Z. Shi, F. Glorius,
Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed C-H Activation: Redox-Neutral and Traceless by N-N Bond Cleavage,
Angew. Chem. Int. Ed. 2013, 52, 12426-12429; Angew. Chem. 2013, 125, 12652-12656. DOI
149) H. Wang, B. Beiring, D.-G. Yu, K. Collins, F. Glorius,
[3]Dendralene Synthesis: Rhodium(III)-Catalyzed Alkenyl C–H Activation and Coupling Reaction with Allenyl Carbinol Carbonate,
Angew. Chem. Int. Ed. 2013, 52, 12430-12434; Angew. Chem. 2013, 125, 12657-12661. DOI
148) D. Zhao§, C. Nimphius§, M. Lindale, F. Glorius,
Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks,
Org. Lett. 2013, 15, 4504-4507. DOI
§ Both authors contributed equally.
147) Z. Shi, D. C. Koester, M. Boultadakis-Arapinis, F. Glorius,
Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds,
J. Am. Chem. Soc. 2013, 135, 12204-12207. DOI
146) N. Kuhl§, N. Schröder§, F. Glorius,
Rh(III)-Catalyzed Halogenation of Vinylic C–H Bonds: Rapid and General Access to Z-Halo Acrylamides,
Org. Lett. 2013, 15, 3860-3863. DOI
§ Both authors contributed equally.
145) D. Zhao, F. Glorius,
Enantioselective Hydrogenation of Isoquinolines,
Angew. Chem. Int. Ed. 2013, 52, 9616-9618; Angew. Chem. 2013, 125, 9794-9796. DOI
144) K. D. Collins, F. Glorius,
A Robustness Screen for the Rapid Assessment of Chemical Reactions,
Nature Chem. 2013, 5, 597-601. DOI
Highlighted in Nature Chem. 2013, 5, 554 - News & Views.
Highlighted in Nachrichten aus der Chemie 2013, 61, 867.
Highlighted in Nature Methods 2013, 10, 699. DOI
Highlighted by the FACULTY of 1000 (F1000Prime). LINK
143) D.-G. Yu§, M. Suri§, F. Glorius,
RhIII/CuII-Cocatalyzed Synthesis of 1H-indazoles through C–H Amidation and N–N Bond Formation,
J. Am. Chem. Soc. 2013, 135, 8802-8805. DOI
§ Both authors contributed equally.
142) D.-T. D. Tang, K. Collins, F. Glorius,
Completely Regioselective Direct C–H Functionalization of Benzo[b]thiophenes Using a Simple Heterogeneous Catalyst,
J. Am. Chem. Soc. 2013, 135, 7450–7453. DOI
Highlighted in Nature 2013, 498, 275 - Research Highlights.
Highlighted in Synfacts 2013, 9, 0908.
Highlighted in ChemCatChem 2013, early view. DOI
Highlighted in Today's Science September 2013. Link
141) Z. Shi, M. Boultadakis-Arapinis, F. Glorius,
Rh(III)-Catalyzed Dehyrogenative Alkylation of (Hetero)Arenes with Allylic Alcohols, Allowing an Aldol Condensation to Indenes,
Chem. Commun. 2013, 49, 6489-6491. DOI
140) N. Ortega, D.-T. D. Tang, S. Urban, D. Zhao, F. Glorius,
Ruthenium-NHC Catalyzed Asymmetric Hydrogenation of Indolizines: Access to Indolizidine Alkaloids,
Angew. Chem. Int. Ed. 2013, 52, 9500-9503; Angew. Chem. 2013, 125, 9678-9681. DOI
Highlighted in Synfacts 2013, 9, 1183.
Highlighted in Organic Chemistry Highlights 2014, November 17.
139) D. Zhao, B. Beiring, F. Glorius,
Ruthenium-NHC Catalyzed Asymmetric Hydrogenation of Flavones and Chromones: General Access to Enantio-enriched Flavanones, Flavanols, Chromanones and Chromanols,
Angew. Chem. Int. Ed. 2013, 52, 8454-8458; Angew. Chem. 2013, 125, 8612-8616. DOI
Highlighted in Synfacts 2013, 9, 1184.
138) C. Grohmann, H. Wang, F. Glorius,
Rh[III]-catalyzed C-H Amidation using Aroyloxycarbamates to give N-Boc protected Arylamines,
Org. Lett. 2013, 15, 3014-3017. DOI
137) K. D. Collins, F. Glorius,
Employing a Robustness Screen: Rapid Assessment of Rhodium(III)-catalysed C-H Activation Reactions,
Tetrahedron 2013, 69, 7817-7825. DOI
136) B. Sahoo, M. N. Hopkinson, F. Glorius,
Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes,
J. Am. Chem. Soc. 2013, 135, 5505–5508. DOI
Highlighted in Nachrichten aus der Chemie 2013, 61, 620.
135) Z. Shi, C. Grohmann, F. Glorius,
Mild Rh(III)-Catalyzed Cyclization of Amides with a,ß-Unsaturated Aldehydes and Ketones to Azepinones: Application to the Synthesis of the Homoprotoberberine Framework,
Angew. Chem. Int. Ed. 2013, 52, 5393-5397; Angew. Chem. 2013, 125, 5503-5507. DOI
Highlighted in Synfacts 2013, 9, 0828.
134) Z. Shi§, M. Suri§, F. Glorius,
Aerobic Synthesis of Pyrroles and Dihydropyrroles from Imines: Palladium(II)-Catalyzed Intramolecular C-H Dehydrogenative Cyclization,
Angew. Chem. Int. Ed. 2013, 52, 4892–4896; Angew. Chem. 2013, 52, 4992–4996. DOI
§ Both authors contributed equally.
133) N. Ortega, C. Richter, F. Glorius,
N-Formylation of Amines by Methanol Activation,
Org. Lett. 2013, 15, 1776–1779. DOI
132) J. Wencel-Delord,* F. Glorius,*
C–H bond activation enables the rapid construction and late-stage diversification of functional molecules,
Nature Chem. 2013, 5, 369–375. DOI
131) H. Wang, N. Schröder, F. Glorius,
Mild Rh(III)-Catalyzed Direct C-H Allylation of Arenes with Allyl Carbonates,
Angew. Chem. Int. Ed. 2013, 52, 5386-5389; Angew. Chem. 2013, 125, 5495-5499. DOI
130) J. Hyvl,* D. Agrawal, R. Pohl, M. Suri, F. Glorius, D. Schröder,
Electrospray Ionization Mass Spectrometry Reveals an Unexpected Coupling Product in the Copper-Promoted Synthesis of Pyrazoles,
Organometallics 2013, 32, 807-816. DOI
129) G. Nickerl, A. Notzon, M. Heitbaum, I. Senkovska, F. Glorius,* S. Kaskel,*
Selective Adsorption Properties of Cationic Metal–Organic Frameworks Based on Imidazolic Linker,
Cryst. Growth Des. 2013, 13, 198–203. DOI
128) M. Schedler, D.-S. Wang, F. Glorius,
NHC-Catalyzed Hydroacylation of Styrenes,
Angew. Chem. Int. Ed. 2013, 52, 2585-2589; Angew. Chem. 2013, 125, 2645-2649. DOI
Selected as hot paper by Angewandte Chemie.
Highlighted in Synfacts 2013, 9, 0437.
127) F. W. Patureau, T. Besset, F. Glorius, checked by T. Harada, T. Fukuyama,
Preparation of (E)-N,N-Diethyl-2-styrylbenzamide by Rh-catalyzed C-H activation,
Org. Synth. 2013, 90, 41-51. Link
126) Z. Shi, F. Glorius,
Synthesis of Fluorenones via Quaternary Ammonium Salt-Promoted Intramolecular Dehydrogenative Arylation of Aldehydes,
Chem. Sci. 2013, 4, 829-833. DOI
Highlighted in Synform 2013, 6, A71-A73. DOI
2012
125) H. Wang, C. Grohmann, C. Nimphius, F. Glorius,
Mild Rhodium(III)-Catalyzed C–H Activation and Annulation with Alkyne MIDA Boronates: Short and Efficient Synthesis of Heterocyclic Boronic Acid Derivatives,
J. Am. Chem. Soc. 2012, 134, 19592–19595. DOI
Highlighted in Synfacts 2013, 9, 0261.
124) C. Grohmann, T. Hashimoto, R. Fröhlich, Y. Ohki,* K. Tatsumi,* F. Glorius,*
An Iron(II) Complex of Diamine-Bridged Bis-N-Heterocyclic Carbene,
Organometallics 2012, 31, 8047–8050. DOI
123) H. Wang,* F. Glorius,*
Lending Handedness to the Cyclopentadienyl Ligand,
Science 2012, 338, 479-480. DOI
122) N. E. Wurz, C. G. Daniliuc, F. Glorius,
Highly Enantioselective Intermolecular Stetter Reaction of Simple Acrylates – Synthesis of α-Chiral γ-Ketoesters,
Chem. Eur. J. 2012, 18, 16297–16301. DOI
121) J. Wencel-Delord§, C. Nimphius§, H. Wang, F. Glorius,
Rhodium(III) and Hexabromobenzene – A Catalyst System for the Cross-Dehydrogenative Coupling of Simple Arenes and Heterocycles with Arenes Bearing Directing Groups,
Angew. Chem. Int. Ed. 2012, 51, 13001–13005; Angew. Chem. 2012, 124, 13175-13180. DOI
§ These authors contributed equally.
120) S. Urban,§ B. Beiring,§N. Ortega, D. Paul, F. Glorius,
Asymmetric Hydrogenation of Thiophenes and Benzothiophenes,
J. Am. Chem. Soc. 2012, 134, 15241-15244. DOI
§ These authors contributed equally.
Highlighted in Synfacts 2012, 8, 1327.
119) I. Piel, J. V. Dickschat, T. Pape, F. E. Hahn,* F. Glorius,*
A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene,
Dalton Trans. 2012, 41, 13788-13790. DOI
118) H. C. Hoffmann, S. Paasch, P. Müller, I. Senkovska, M. Padmanaban, F. Glorius, S. Kaskel, E. Brunner,*
Chiral Recognition in Metal-Organic Frameworks Studied by Solid-State NMR Spectroscopy Using Chiral Solvating Agents,
Chem. Commun. 2012, 48, 10484-10486. DOI
117) F. W. Patureau,* J. Wencel-Delord, F. Glorius,*
Cp*Rh-Catalyzed C–H Activations: Versatile Dehydrogenative Cross-Couplings of Csp2 C–H Positions with Olefins, Alkynes, and Arenes,
Aldrichimica Acta 2012, 45, 31-41. Link
116) F. W. Patureau,* T. Besset, R. Fröhlich, F. Glorius,*
On the selectivity in some Rh(III) catalyzed C-H activation cross-couplings;
De la sélectivité dans des réactions d'hétéro-couplage par C-H activation catalysées au Rh(III),
C. R. Chim. 2012, 15, 1081-1085. DOI
115) Z. Shi, F. Glorius,
Efficient and Versatile Indole Synthesis from Enamines and Imines via Cross-Dehydrogenative Coupling,
Angew. Chem. Int. Ed. 2012, 51, 9220-9222; Angew. Chem. 2012, 124, 9354-9356. DOI
114) K. Nagura, S. Saito, R. Fröhlich, F. Glorius,* S. Yamaguchi,*
N-Heterocyclic Carbene Borane as an Electron Donating and Accepting Component of π-Conjugated Systems,
Angew. Chem. Int. Ed. 2012, 51, 7762-7766; Angew. Chem. 2012, 124, 7882-7886. DOI
113) N. Kuhl, M. N. Hopkinson, J. Wencel-Delord, F. Glorius,
Beyond Directing Groups: Transition Metal-Catalyzed C H Activation of Simple Arenes,
Angew. Chem. Int. Ed. 2012, 51, 10236-10254; Angew. Chem. 2012, 124, 10382-10401. DOI
112) C. Lohre, C. Nimphius, M. Steinmetz, S. Würtz, R. Fröhlich, C. G. Daniliuc, S. Grimme, F. Glorius,
Investigation of the complexation behavior and catalysis of IBiox-[(-)-menthyl]·HOTf,
Tetrahedron 2012, 68, 7636-7644. DOI
111) N. Kuhl, M. N. Hopkinson, F. Glorius,
Selective Rh(III)-Catalyzed Cross-Dehydrogenative Coupling of Furan and Thiophene Derivatives,
Angew. Chem. Int. Ed. 2012, 51, 8230-8234; Angew. Chem. 2012, 124, 8354-8358. DOI
110) M. Suri, T. Jousseaume, J. J. Neumann, F. Glorius,
An efficient copper-catalyzed formation of highly substituted pyrazoles using molecular oxygen as the oxidant,
Green Chem. 2012, 14, 2193-2196. DOI
109) Z. Shi, N. Schröder, F. Glorius,
Rh[III]-Catalyzed Dehydrogenative Heck Reaction (DHR) of Salicylaldehydes,
Angew. Chem. Int. Ed. 2012, 51, 8092-8096; Angew. Chem. 2012, 124, 8216-8220.DOI
Highlighted in Synfacts 2012, 8, 1211.
108) T. Hashimoto, S. Urban, R. Hoshino, Y. Ohki,* K. Tatsumi,* F. Glorius,*
Synthesis of Bis(N-heterocyclic carbene) Complexes of Iron(II) and Their Application in Hydrosilylation and Transfer Hydrogenation,
Organometallics 2012, 31, 4474-4479. DOI
107) M. Schedler, R. Fröhlich, C. G. Daniliuc, F. Glorius,
2,6-Dimethoxyphenyl-substituted N-heterocyclic carbenes (NHCs): a new family of highly electron-rich organocatalysts,
Eur. J. Org. Chem. 2012, 4164-4171. DOI
106) N. Schröder,§ J. Wencel-Delord,§ F. Glorius,
High Yielding, Versatile and Practical [Rh(III)Cp*]-Catalyzed ortho-Bromination and Iodination of Arenes,
J. Am. Chem. Soc. 2012, 134, 8298-8301. DOI
§ Both authors contributed equally to this work.
105) N. Ortega, B. Beiring, S. Urban, F. Glorius,
Highly asymmetric synthesis of (+)-corsifuran A. Elucidation of the electronic requirements in the Ruthenium–NHC catalyzed hydrogenation of benzofurans,
Tetrahedron 2012, 68, 5185-5192.DOI
104) H. Wang, F. Glorius,
Mild Rh(III)-Catalyzed C-H Activation of Aromatic Amide Derivatives and Intermolecular Annulation with Allenes: Efficient Synthesis of 3,4-Dihydroisoquinolin-1(2H)-ones,
Angew. Chem. Int. Ed. 2012,51, 7318-7322; Angew. Chem. 2012, 124, 7430-7434. DOI
Selected as hot paper by Angewandte Chemie.
103) X. Bugaut,* F. Glorius,*
Organocatalytic Umpolung: N-Heterocyclic Carbenes and Beyond,
Chem. Soc. Rev. 2012, 41, 3511-3522. DOI
102) J. Wencel-Delord, C. Nimphius, F. W. Patureau, F. Glorius,
Undirected C-H Bond Activation of Arenes: [Rh(III)Cp*]-Catalyzed Dehydrogenative Alkene-Arene Coupling as New Pathway for the Selective Synthesis of Highly Substituted Z-Olefins,
Chem. Asian J. 2012, 7, 1208-1212. DOI
(Special issue celebrating 150 years of German-Japanese relations)
101) J. Wencel-Delord, C. Nimphius, F. W. Patureau, F. Glorius,
[Rh(III)Cp*]-Catalyzed Dehydrogenative Aryl-Aryl Bond Formation,
Angew. Chem. Int. Ed. 2012, 51, 2247-2251; Angew. Chem. 2012, 124, 2290-2294. DOI
Selected as hot paper by Angewandte Chemie.
100) N. Ortega, S. Urban, B. Beiring F. Glorius,
Ruthenium-NHC Catalyzed Highly Asymmetric Hydrogenation of Benzofurans,
Angew. Chem. Int. Ed. 2012, 51, 1710-1713; Angew. Chem. 2012, 124, 1742-1745. DOI
Selected as hot paper by Angewandte Chemie.
Highlighted in Synfacts 2012, 8, 519.
99) C. Grohmann, H. Wang, F. Glorius,
Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room Temperature,
Org. Lett. 2012, 14, 656-659. DOI
98) N. Schröder, T. Besset, F. Glorius,
Synthesis of Olefin-Oxazoline-Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination,
Adv. Synth. Catal. 2012, 354, 579-583. DOI
97) C. Richter, K. V. S. Ranganath, F. Glorius,
Enantioselective α-Arylation of Cyclic Ketones Catalyzed by a Combination of an Unmodified Cinchona Alkaloid and a Palladium Complex,
Adv. Synth. Catal. 2012, 354, 377-382. DOI
Highlighted in Synfacts 2012, 8, 520.
2011
96) F. W. Patureau, C. Nimphius, F. Glorius,
Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes,
Org. Lett. 2011, 13, 6346-6349. DOI
95) F. Liu, X. Bugaut, M. Schedler, R. Fröhlich, F. Glorius,
Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes,
Angew. Chem. Int. Ed. 2011, 50, 12626-12630;Angew. Chem. 2011, 123, 12834-12838. DOI
94) M. Padmanaban, P. Müller, C. Lieder, K. Gedrich, R. Grünker, V. Bon, I. Senkovska, S. Baumgärtner, S. Opelt, S. Paasch, E. Brunner, F. Glorius,* E. Klemm,* S. Kaskel,*
Application of a Chiral Metal–organic Framework in Enantioselective Separation,
Chem. Commun. 2011, 47, 12089-12091. Advance Article. DOI
93) M. Padmanaban, A. T. Biju, F. Glorius,
Efficient Synthesis of Benzofuranones: N-Heterocyclic Carbene (NHC)/Base-Catalyzed Hydroacylation–Stetter–Rearrangement Cascade,
Org. Lett. 2011, 13, 5624-5627. DOI
92) T. Dröge§, A. Notzon§, R. Fröhlich, F. Glorius,
Palladium-catalyzed C-H bond Functionalization of a MOF: Mild, Selective and Efficient,
Chem. Eur. J. 2011, 17, 11974-11977. DOI
§ Both authors contributed equally to this work. This paper we would like to highlight, since it represents the first metal-catalyzed C-H functionalization of a MOF. Please, check it out!
91) K. V. S. Ranganath, A. Schäfer, F. Glorius,
Comparison of Superparamagnetic Fe3O4 Supported N-Heterocyclic carbene (NHC) Based Catalysts for Enantioselective Allylation,
ChemCatChem 2011, 3,1889-1891. DOI
90) A. T. Biju, M. Padmanaban, N. E. Wurz, F. Glorius,
N-Heterocyclic Carbene (NHC)-Catalyzed Umpolung of Michael Acceptors for Intermolecular Reactions,
Angew. Chem. Int. Ed. 2011, 50, 8412-8415; Angew. Chem. 2011, 123, 8562-8565. DOI
89) A. T. Biju, N. Kuhl, F. Glorius,
Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners,
Acc. Chem. Res. 2011, 44, 1182-1195. DOI
88) I. Piel,§ M. D. Pawelczyk,§ K. Hirano, R. Fröhlich, F. Glorius,
A Family of Thiazolium Salt Derived N-Heterocyclic Carbenes (NHCs) for Organocatalysis: Synthesis, Investigation and Application in Cross-Benzoin Condensation,
Eur. J. Org. Chem. 2011, 5475-5484. DOI
§ Both authors contributed equally to this work.
87) X. Bugaut, F. Glorius,
Palladium-Catalyzed Selective Dehydrogenative Cross-Coupling of Heteroarenes,
Angew. Chem. Int. Ed. 2011, 50, 7479-7481; Angew. Chem. 2011, 123, 7618-7620. DOI
86) J. Wencel-Delord, T. Dröge, F. Liu, F. Glorius,
Towards Mild Metal-Catalyzed C-H Bond Activation,
Chem. Soc. Rev. 2011, 40, 4740-4761. DOI
85) T. Besset, N. Kuhl, F. W. Patureau, F. Glorius,
RhIII-Catalyzed Oxidative Olefination of Vinylic C-H Bonds: Efficient and Selective Access to Di-unsaturated α-Amino Acid Derivatives and other Linear 1,3-Butadienes,
Chem. Eur. J. 2011,17, 7167-7171. DOI
84) J. Willwacher, S. Rakshit, F. Glorius,
Investigating N-Methoxy-N’-Aryl Ureas in Oxidative C-H Olefination Reactions: An Unexpected Oxidation Behaviour,
Org. Biomol. Chem. 2011, 9, 4736-4740. DOI
83) K. Hirano,* I. Piel, F. Glorius,*
Dual Activation in NHC-Organocatalysis,
Chem. Lett. 2011, 40, 786-791. DOI
82) X. Bugaut, F. Liu, F. Glorius,
N-Heterocyclic Carbene (NHC)-Catalyzed Intermolecular Hydroacylation of Cyclopropenes,
J. Am. Chem. Soc. 2011, 133, 8130-8133. DOI
Highlighted in Synfacts 2011, 8, 902.
81) C. Lohre, T. Dröge, C. Wang, F. Glorius,
Nickel-catalyzed Cross-Coupling of Aryl Bromides with Tertiary Grignard Reagents Utilizing Donor-functionalized N-Heterocyclic Carbenes (NHCs),
Chem. Eur. J. 2011, 17, 6052-6055. DOI
80) J. J. Neumann, S. Rakshit, T. Dröge, S. Würtz, F. Glorius,
Exploring the Oxidative Cyclization of Substituted N-Aryl Enamines: Pd-catalyzed Formation of Indoles from Anilines,
Chem. Eur. J. 2011, 17, 7298-7303.DOI
Highlighted in Synfacts 2011, 8, 829.
79) I. Piel, M. Steinmetz, K. Hirano, R. Fröhlich, S. Grimme,* F. Glorius,*
Highly Asymmetric NHC-Catalyzed Hydroacylation of Unactivated Alkenes,
Angew. Chem. Int. Ed. 2011, 50, 4983-4987; Angew. Chem. 2011, 123, 5087-5091. DOI
Selected as very important paper (VIP) by Angewandte Chemie.
Highlighted in Synfacts 2011, 7, 789.
78) M. Rose, A. Notzon, M. Heitbaum, G. Nickerl, S. Paasch, E. Brunner, F. Glorius,* S. Kaskel,*
N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts,
Chem. Commun. 2011, 47, 4814-4816. DOI
77) Y. Loewer, C. Weiss, A. T. Biju, R. Fröhlich, F. Glorius,
Synthesis and Application of a Chiral Diborate,
J. Org. Chem. 2011, 76, 2324-2327. DOI
76) S. Rakshit, C. Grohmann, T. Besset, F. Glorius,
Rh[III]-Catalyzed Directed C-H Olefination Using an Internal Oxidant: Mild, Efficient and Versatile,
J. Am. Chem. Soc. 2011, 133, 2350-2353. DOI
75) S. Urban, N. Ortega, F. Glorius,
Ligand-Controlled Highly Regioselective and Asymmetric Hydrogenation of Quinoxalines Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes,
Angew. Chem. Int. Ed. 2011, 50, 3803-3806; Angew. Chem. 2011, 123, 3887-3890. DOI
Selected as hot paper by Angewandte Chemie.
Highlighted in Synfacts 2011, 6, 633.
74) F. W. Patureau, T. Besset, N. Kuhl, F. Glorius,
Diverse Strategies Towards Indenol and Fulvene Derivatives: Rh-catalyzed C-H Activation of Aryl Ketones Followed by Coupling With Internal Alkynes,
J. Am. Chem. Soc. 2011, 133, 2154-2156.DOI
73) F. W. Patureau,* F. Glorius,*
Oxidizing Directing Groups Enabling Efficient and Innovative C-H Activation Reactions,
Angew. Chem. Int. Ed. 2011, 50, 1977-1979; Angew. Chem. 2011, 123, 2021-2023. DOI
72) K. V. S. Ranganath, F. Glorius,
Superparamagnetic Nanoparticles for Asymmetric Catalysis – A Perfect Match,
Catalysis Science & Technology 2011, 1, 13-22 (inaugural issue). DOI
71) T. Jousseaume, N. E. Wurz, F. Glorius,
Highly Enantioselective Synthesis of α-Amino Acid Derivatives by an N-Heterocyclic Carbene (NHC)-catalyzed Intermolecular Stetter Reaction,
Angew. Chem. Int. Ed. 2011, 50, 1410-1414; Angew. Chem. 2011, 123, 1446-1450. DOI
Highlighted twice in Synfacts 2011, 4, 446 (Methodology) and in Synfacts 2011, 5, 466 (Synthesis of Potential Drug).
70) F. W. Patureau, T. Besset, F. Glorius,
Rhodium Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides,
Angew. Chem. Int. Ed. 2011, 50, 1064-1067; Angew. Chem. 2011, 123, 1096-1099. DOI
69) M. Padmanaban, A. T. Biju, F. Glorius,
N-Heterocyclic Carbene-Catalyzed Cross-Coupling of Aromatic Aldehydes with Activated Alkyl Halides,
Org. Lett. 2011, 13, 98-101. DOI
Highlighted in Synfacts 2011, 2, 209.
68) N. Kuhl, F. Glorius,
Direct and Efficient N-Heterocyclic Carbene-catalyzed Hydroxymethylation of Aldehydes,
Chem. Commun. 2011, 47, 573-575. DOI
Invited to and part of the "Emerging Investigators" issue of Chemical Communications.
67) K. Gedrich, M. Heitbaum, A. Notzon, I. Senkovska, R. Fröhlich, J. Getzschmann, U. Mueller, F. Glorius,* S. Kaskel*,
A New Family of Chiral Metal-Organic Frameworks,
Chem. Eur. J. 2011, 17, 2099-2106. DOI
2010
66) A. T. Biju, F. Glorius,
Intermolecular N-Heterocyclic Carbene-catalyzed Hydroacylation of Arynes,
Angew. Chem. Int. Ed. 2010, 49, 9761-9764; Angew. Chem. 2010, 122, 9955-9958.DOI
Selected as hot paper by Angewandte Chemie.
Highlighted in Synfacts 2011, 1, 95.
65) J. V. Dickschat, S. Urban, T. Pape, F. Glorius,* F. E. Hahn,*
Sterically Demanding and Chiral N,N'-Disubstituted N-Heterocyclic Germylenes and Stannylenes,
Dalton Trans. 2010, 39, 11519-11521. DOI
64) C. Wang,* S. Rakshit, F. Glorius,*
Palladium-catalyzed Intermolecular Decarboxylative Coupling of 2-Phenylbenzoic Acids with Alkynes via C-H and C-C Bond Activation,
J. Am. Chem. Soc. 2010, 120, 14006-14008. DOI
Highlighted in Synfacts 2011, 2, 201.
63) J. J. Neumann, M. Suri, F. Glorius,
Efficient Synthesis of Pyrazoles: Oxidative C-C/N-N Bond Formation Cascade,
Angew. Chem. Int. Ed. 2010, 49, 7790-7794; Angew. Chem. 2010, 122, 7957-7961. DOI
62) K. V. S. Ranganath, J. Kloesges, A. H. Schäfer, F. Glorius,
Asymmetric Nanocatalysis: N-Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd Nanoparticles,
Angew. Chem. Int. Ed. 2010, 49, 7786-7789; Angew. Chem. 2010, 122, 7952-7956.DOI
Highlighted in Synfacts 2011, 1, 109.
61) F. W. Patureau, F. Glorius,
Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides,
J. Am. Chem. Soc. 2010, 132, 9982-9983. DOI
60) S. Rakshit, F. W. Patureau, F. Glorius,
Pyrrole Synthesis via Allylic sp3 C-H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes,
J. Am. Chem. Soc. 2010, 132, 9585-9587. DOI
Highlighted in Synfacts 2010, 6, 716.
59) T. Dröge, F. Glorius,
The Measure of All Rings - N-Heterocyclic Carbenes,
Angew. Chem. Int. Ed. 2010, 49, 6940-6952;Angew. Chem. 2010, 122, 7094-7107. DOI
58) A. T. Biju, N. E. Wurz, F. Glorius,
N-Heterocyclic Carbene-Catalyzed Cascade Reaction Involving the Hydroacylation of Unactivated Alkynes,
J. Am. Chem. Soc. 2010, 132, 5970-5971. DOI
Highlighted in Synfacts 2010, 6, 716.
57) B. T. Hahn, F. Tewes, R. Fröhlich, F. Glorius,
Olefin-oxazolines (OlefOx) - Highly Modular, Easily Tunable Ligands for Asymmetric Catalysis,
Angew. Chem. Int. Ed. 2010, 122, 1143-1146; Angew. Chem. 2010,49, 1161-1164. DOI
Selected as hot paper by Angewandte Chemie.
56) T. Dröge, F. Glorius,
NHC - Ligand der Ideen,
Nachrichten aus der Chemie 2010, 58, 112-117. DOI
The publication was selected for the cover picture of the corresponding issue.
55) F. Glorius,
Stereochemistry by Remote Control (News & Views),
Nature Chem. 2010, 2, 78-80. DOI
54) M. Heitbaum, R. Fröhlich, F. Glorius,
Diastereoselective Hydrogenation of Substituted Quinolines to Enantiomerically Pure Decahydroquinolines,
Adv. Synth. Catal. 2010, 352, 357-362. DOI
Highlighted in Synfacts 2010, 05, 572.
2009
53) K. Hirano, A. T. Biju, F. Glorius,
Copper-Catalyzed Synthesis of 2-Unsubstituted, N-Substituted Benzimidazoles,
J. Org. Chem. 2009, 74, 9570-9572. DOI52) K. Hirano, A. T. Biju, I. Piel, F. Glorius,
N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds,
J. Am. Chem. Soc. 2009, 131, 14190. DOI
Highlighted in Synfacts 2009, 12, 1404.51) A. T. Biju, K. Hirano, R. Fröhlich, F. Glorius,
Switching the Electron-Donor Properties of N-Heterocyclic Carbenes by a Facile Deprotonation Strategy,
Chem. Asian J. 2009, 4, 1786-1789. DOI50) F. Glorius, J. J. Neumann,
Handbook of Green Chemistry - Green Catalysis (Book review),
Angew. Chem. Int. Ed. 2009, 48, 7120-7121; Angew. Chem. 2009, 121, 7256-7257. DOI49) J. J. Neumann, S. Rakshit, T. Dröge, F. Glorius,
Pd-Catalyzed Amidation of Unactivated sp3 C-H Bonds: from Anilines to Indolines,
Angew. Chem. Int. Ed. 2009, 48, 6892-6895; Angew. Chem. 2009, 121, 7024-7027. DOI
Selected as hot paper by Angewandte Chemie.48) S. Urban, M. Tursky, R. Fröhlich, F. Glorius,
Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes,
Dalton Trans. 2009, 6934-6940. DOI47) S. Würtz, C. Lohre, R. Fröhlich, K. Bergander, F. Glorius,
IBiox[(-)-menthyl] – a Sterically Demanding Chiral NHC Ligand,
J. Am. Chem. Soc. 2009, 131, 8344-8345. DOI
Highlighted in Synfacts 2009, 9, 1011.46) C. Wang, F. Glorius,
Controlled Iterative Cross-couplings: On the Way to the Automation of Organic Synthesis,
Angew. Chemie Int. Ed. 2009, 48, 5240-5244, Angew. Chem. 2009, 121, 5342-5346. DOI45) C. Wang, I. Piel, F. Glorius,
Palladium-catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C-H Activation,
J. Am. Chem. Soc. 2009, 131, 4194-4195. DOI44) K. Hirano, S. Urban, C. Wang, F. Glorius,
A Modular Synthesis of Highly Substituted Imidazolium Salts,
Org. Lett. 2009, 11, 1019-1022. DOI43) H. Richter, H. Schwertfeger, P. R. Schreiner,* R. Fröhlich, F. Glorius,*
Synthesis of Diamantane Derived N-Heterocyclic Carbenes (IDAd) and Applications in Catalysis,
Synlett 2009, 193-197.2008
42) B. T. Hahn, R. Fröhlich, K. Harms, F. Glorius,
First Proline-catalyzed Highly Enantio- and anti-Selective Mannich Reaction of Unactivated Ketones - Synthesis of Chiral α-Amino Acids,
Angew. Chem. Int. Ed. 2008, 47, 9985-9988; Angew. Chem. 2008, 120, 10134-10137. DOI
Highlighted in Synfacts 2009, 2, 213.41) R. Lebeuf, K. Hirano, F. Glorius,
Palladium catalyzed C-Allylation of Benzoins & an NHC-catalyzed Three Component Coupling Derived Thereof - Compatibility of NHC- and Pd-Catalysts,
Org. Lett. 2008, 10, 4243-4246. DOI40) F. Glorius,
Asymmetric Cross-Coupling of Non-Activated Secondary Alkyl Halides,
Angew. Chem. Int. Ed. 2008, 47, 8347-8349; Angew. Chem. 2008, 120, 8474-8476. DOI39) S. Würtz, S. Rakshit, J. J. Neumann, T. Dröge, F. Glorius,
Palladium-Catalyzed Oxidative Cyclization of N-Aryl Enamines: From Anilines to Indoles,
Angew. Chem. Int. Ed. 2008, 47, 7230-7233; Angew. Chem. 2008, 120, 7340-7343. DOI
Selected as hot paper by Angewandte Chemie.38) B. Hahn, K. Schwekendiek, F. Glorius,
Efficient Oxidative Synthesis of (-)-2-tert-butyl-(4S)-benzyl-(1,3)-oxazoline,
Org. Synth. 2008, 85, 267-277. DOI37) C. Lohre, R. Fröhlich, F. Glorius,
Thiazole-annelated Imidazolium Salts: A New Architecture for N-Hetereocyclic Carbenes,
Synthesis 2008, 2221-2228. DOI36) F. Glorius, K. Hirano,
Nucleophilic Carbenes as Organocatalysts,
Ernst Schering Foundation Symposium Proceedings 2008, Vol. 2, 159-181. DOI35) S. Würtz, F. Glorius,
Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions,
Acc. Chem. Res. 2008, 41, 1523-1533. DOI34) K. Hirano, I. Piel, F. Glorius,
Diastereoselective Synthesis of Trifluoromethylated γ-Butyrolactones via N-Heterocyclic Carbene-catalyzed Conjugated Umpolung of a,ß-unsaturated Aldehydes,
Adv. Synth. Catal. 2008, 350, 984-988. DOI2007
33) F. Tewes, A. Schlecker, K. Harms, F. Glorius,
Carbohydrate-Containing N-Heterocyclic Carbene Complexes,
J. Organomet. Chem. 2007, 692, 4593-4602. DOI32) K. Schuh (nee Müller), F. Glorius,
A Domino Copper-Catalyzed C-N-/C-O-Coupling Process for the Synthesis of Oxazoles,
Synthesis 2007, 2297-2306. DOI31) X. Xie, S Tschan, F. Glorius,
Determination of the Stereochemistry of γ-Butyrolactones by DPFGSE-NOE Experiments,
Magn. Reson. Chem. 2007, 45, 381-388. DOI30) W. Schrader, P. P. Handayani, C. Burstein, F. Glorius,
Investigating Organocatalytic Reactions: Mass Spectrometric Studies of a Conjugate Umpolung Reaction,
Chem. Commun. 2007, 716-718. DOIF. Glorius (Editor),
N-Heterocyclic Carbenes in Transition-Metal Catalysis,
Topics in Organometallic Chemistry, Springer 2007. DOI29) F. Glorius,
N-Heterocyclic Carbenes in Transition-Metal Catalysis,
in Topics in Organometallic Chemistry, pp. 1-20, Springer 2007. DOI28) I. Escher, F. Glorius,
Product Class 7: Polyenales,
Science of Synthesis 2007, 25, 711-731.27) I. Escher, F. Glorius,
Product Class 8: a,ß-unsaturated Aldehydes,
Science of Synthesis 2007, 25, 733-777.before 2007
2006
26) K. Schwekendiek, F. Glorius,
Efficient Oxidative Synthesis of 2-Oxazolines,
Synthesis 2006, 2996-3002. DOI25) G. Altenhoff, S. Würtz, F. Glorius,
The First Palladium-catalyzed Sonogashira Coupling of Unactivated Secondary Alkyl Bromides,
Tetrahedron Lett. 2006, 47, 2925-2928. DOI24) C. Burstein, S. Tschan, X. Xie, F. Glorius,
N-Heterocyclic Carbene-Catalyzed Conjugate Umpolung for the Synthesis of γ-Butyrolactones (feature article),
Synthesis 2006, 2418-2439. DOI23) Y. Gnas, F. Glorius,
Chiral Auxiliaries - Principles and Recent Applications,
Synthesis 2006, 1899-1930. DOI22) M. Heitbaum, F. Glorius, I. Escher,
Asymmetric Heterogeneous Catalysis,
Angew. Chem. Int. Ed. 2006, 45, 4732-4762; Angew. Chem. 2006, 118, 4850-4881. DOI2005
21) F. Glorius,
Metal-Catalyzed Cross-Coupling Reactions (Book review),
Angew. Chem. Int. Ed. 2005, 44, 1157; Angew. Chem. 2005, 117, 1181. DOI20) C. Burstein, F. Glorius,
Asymmetric Organocatalysis (Book review),
Angew. Chem. 2005, 117, 4357-4358. DOI19) D. A. Evans, F. Glorius, J. D. Burch,
Complex Aldol Reactions for the Construction of Dense Polyol Stereoarrays: Synthesis of the C33-C36 Region of Aflastatin A,
Org. Lett. 2005, 7, 3331-3333. DOI18) F. Glorius,
Asymmetric Hydrogenation of Heteroaromatic Compounds,
Org. Biomol. Chem. 2005, 3, 4171-4175. DOI17) C. Burstein, C. W. Lehmann, F. Glorius,
Imidazo[1,5-a]pyridine-3-ylidenes - Pyridine Derived N-Heterocyclic Carbene Ligands,
Tetrahedron 2005, 61, 6207-6217. DOI2004
16) F.Glorius, G. Altenhoff,
14. International Symposium on Homogeneous Catalysis (ISHC) (conference report),
Nachr. Chem. Tech. 2004 , 52, 948.15) F. Glorius,
Chiral Reagents for Asymmetric Synthesis (Book review),
Angew. Chem. Int. Ed. 2004, 43, 1619-1620; Angew. Chem. 2004, 116, 1647-1648. DOI14) F. Glorius, N. Spielkamp, S. Holle, R. Goddard, C. W. Lehmann,
Efficient Asymmetric Hydrogenation of Pyridines,
Angew. Chem. Int. Ed. 2004, 43, 2850-2852; Angew. Chem. 2004, 116, 2910-2912. DOI
The publication was selected for the cover picture of the corresponding issue.13) F. Glorius,
Chiral Olefin Ligands - New "Spectators" in Asymmetric Catalysis (Highlight),
Angew. Chem. Int. Ed. 2004, 43, 3364-3366; Angew. Chem. 2004, 116, 3444-3446. DOI12) B. Scheiper, F. Glorius, A. Leitner, A. Fürstner,
Catalysis-Based Enantioselective Total Synthesis of the Macrocyclic Spermidine Alkaloid Isooncinotine,
Proc. Natl. Acad. Sci. USA 2004, 101, 11960-11965. DOI11) G. Altenhoff, F. Glorius,
A Domino Copper-Catalyzed C-N-/C-O-coupling for the Conversion of Primary Amides into Benzoxazoles,
Adv. Synth. Catal. 2004, 346, 1661-1664. DOI10) G. Altenhoff, R. Goddard, C. W. Lehmann, F. Glorius,
Sterically Demanding, Bioxazoline Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis,
J. Am. Chem. Soc. 2004, 126, 15195-15201. DOI9) F. Glorius, C. Burstein,
Conjugate Umpolung of a,ß-Unsaturated Aldehydes for the Synthesis of γ-Butyrolactones,
Angew. Chem. Int. Ed. 2004, 43, 6205-6208; Angew. Chem. 2004, 116, 6331-6334. DOI2003
8) G. Altenhoff, R. Goddard, C. W. Lehmann, F. Glorius,
An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature,
Angew. Chem. Int. Ed. 2003, 42, 3690-3693; Angew. Chem. 2003, 115, 3818-3821. DOI
*See:
Highlight on adaptable ligands: K. Burgess, Chemistry & Industry 2003, 32 (17th November). See also: Highlight on Rational Ligand Design for the Suzuki-Miyaura-Coupling: M. Miura, Angew. Chem. Int. Ed. 2004, 43, 2201; Angew. Chem. 2004, 116, 2251.7) F. Glorius,
Palladium-Catalyzed Heck-Type Reaction of 2-Chloro Acetamides With Olefins,
Tetrahedron Lett. 2003, 44, 5751-5754. DOI2002
6) F. Glorius, G. Altenhoff, R. Goddard, C. W. Lehmann,
Oxazolines as Chiral Building Blocks for Imidazolium Salts and N-heterocyclic Carbene Ligands,
Chem. Commun. 2002, 2704-2705. DOI2001
5) F. Glorius, M. Neuburger, A. Pfaltz,
Highly Enantio- and Regioselective Allylic Alkylations Catalyzed by Chiral [Bis(dihydrooxazole)]molybdenum Complexes,
Helv. Chim. Acta 2001, 84, 3178-3196. DOI1999
4) U. Wörsdörfer, F. Vögtle, M. Nieger, M. Waletzke, S. Grimme, F. Glorius, A. Pfaltz,
A New Planar Chiral Bipyridine Ligand,
Synthesis 1999, 597-602. DOI3) U. Wörsdörfer, F. Vögtle, F. Glorius, A. Pfaltz,
A New Planar Chiral Bipyridine Ligand: Pyrid-2-yl[2](1,4)benzeno[2](5,8)quinolino-phane,
J. Prakt. Chem. 1999, 341, 445-448. DOI2) F. Glorius, A. Pfaltz,
Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands,
Org. Lett. 1999, 1, 141-144. DOI1) P. A. Wender, F. Glorius, C. O. Husfeld, E. Langkopf, J. A. Love,
Transition Metal-Catalyzed [5+2] Cycloadditions of Allenes and Vinylcyclopropanes: First Studies of Endo-Exo Selectivity, Chemoselectivity, Relative Stereochemistry, and Chirality Transfer,
J. Am. Chem. Soc. 1999, 121, 5348-5349. DOI