Dr. Chaohuang Chen
group of Prof. G. Erker
Corrensstrasse 40
48149 Munster
Lab. No .: 2.31
phone: +49 251 83-39741
+49 251 83-33224
email: cchen1@uni-muenster.de
Member of the group since: 01/ 2019
Research interest : Boron chemistry
PdD degree thesis: Palladium-Catalyzed Trifluoromethoxylation of Alkenes. Shanghai Institute of Organic Chemistry (CAS), Shanghai, China, 07/ 2017
Publications:
1. Chen, C.; Daniliuc, C. G.; Kehr, G.; Erker, G. N-Heterocyclic Carbene Stabilized 1-Bora-1,3-butadienes. J. Am. Chem. Soc. 2021, 143, 21312–21320.
2. Chen, C.; Daniliuc, C. G.; Kehr, G.; Erker, G. Formation and Cycloaddition Reactions of a Reactive Boraalkene Stabilized Internally by N-Heterocyclic Carbene. Angew. Chem. Int. Ed. 2021, 60, 19905-19911.
3. Chen, C.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Kehr, G.; Erker, G. A BH Borenium-Derived Thioxoborane, Its Persulfide, and Their Li+-Induced Reactions with Alkynes and with Carbon Dioxide. J. Am. Chem. Soc. 2020, 142, 19763-19771.
4. Chen, C.; Li, J.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Kehr, G.; Erker, G. The [(NHC)B(H)C6F5]+ Cations and their [B](H)-CO Borane Carbonyls. Angew. Chem., Int. Ed. 2020, 59, 21460-21464.
5. Chen, C.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Kehr, G.; Erker, G. A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair. Chem. Commun . 2020 , 56 , 8806-8809.
6. Chen, C .; Pflüger, P. M.; Chen, P .; Liu, G. * Palladium (II) -Catalyzed Enantioselective Aminotrifluoromethoxylation of Unactivated Alkenes using CsOCF 3 as a Trifluoromethoxide Source. Angew. Chem. Int. Ed. 2019 , 58, 2392. (Highlighted by Synfacts.)
7. Qi, X .; † Chen, C .; † Hou, C .; Fu, L .; Chen, P .; Liu, G. * Enantioselective Pd (II) -Catalyzed Intramolecular Oxidative 6-endo Aminoacetoxylation of Unactivated Alkenes. J. Am. Chem. Soc. 2018 , 140 , 7415. ( † Equal contribution)
8. Chen, C .; Luo, Y .; Fu, L .; Chen, P .; Lan, Y .; * Liu, G. * Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: Trifluoromethoxypalladation Initiated by Pd (IV). J. Am. Chem. Soc. 2018 , 140 , 1207.
9. Chen, C .; Chen, P .; Liu, G. * Palladium-Catalyzed Intramolecular Amino-Trifluoromethoxylation of Alkenes. J. Am. Chem. Soc. 2015 , 137 , 15648.
10. Chen, C .; Ouyang, L .; Lin, Q .; Liu, Y .; Hou, C .; Yuan, Y .; Weng, Z. * Synthesis of Cu (I) Trifluoromethylselenates for Trifluoromethylselenolation of Aryl and Alkyl Halides. Chem. Eur. J. 2014 , 20 , 657.
11. Chen, C .; † Hou, C .; † Wang, Y .; Andy Hor, TS; * Weng, Z. * Copper-Catalyzed Trifluoromethylselenolation of Aryl and Alkyl Halides: the Silver Effect in Transmetalation. Org. Lett. 2014 , 16 , 524. ( † Equal contribution)
12. Weng, Z.; * He, W .; Chen, C .; Lee, R .; Tan, D .; Lai, Z .; Kong, D .; Yuan, Y .; and Huang, KW. * An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides. Appl. Chem. Int. Ed. 2013 , 52 , 1548.
13. Chen, C .; Weng, Z. * ; Hartwig, JF * Synthesis of Copper (I) Thiolate Complexes in the Thioetherification of Aryl Halides. Organometallics 2012 , 31 , 8031.
Miscellaneous :
Alexander von Humboldt fellowship for postdoc (2019.11-2021.10).