Forschungsbericht 1995-96
	Organisch-Chemisches Institut Corrensstraße 40 D-48149 Münster Tel.: (0251) 83 - 3 32 10 Fax: (0251) 83 - 3 97 72

Forschungsschwerpunkte 1995 - 1996 Fachbereich 17 - Chemie The Organisch-Chemisches Institut Research group Priv.-Doz. Dr. P. Metz

Research group Priv.-Doz. Dr. P. Metz

METZ, Peter, b. 1953; Dr. rer. nat. 1983 (Univ. Münster, H.-J. Schäfer); Postdoctoral Research 1983-1984 (UW Madison, B. M. Trost); Habilitation 1991 (Univ. Münster); Vertretungsprofessor 1992-1993 (Univ. Hamburg), 1994 (Univ. Kiel), 1996 (TU Dresden); Universitätsprofessor 1997 (TU Dresden). SYNTHETIC METHODOLOGY: intramolecular Diels-Alder reactions of vinylsulfonates and vinylsulfonamides, synthetic elaboration of the resultant sultones and sultams; Claisen rearrangements of allyl imidates; SYNTHESIS OF BIOLOGICALLY ACTIVE COMPOUNDS: actic acids; terpenes; enzyme inhibitors. Tel.: 0251 - 83 - 3 32 45; FAX 0251 - 83 - 3 97 72
NEW ADDRESS: Institut für Organische Chemie, TU Dresden, Mommsenstr. 13, D-01062 Dresden Tel.: 0351 - 463 - 7006; FAX 0351 - 463 - 3162, E-MAIL metz@coch01.chm.tu-dresden.de

Publications:

Metz, M., M. Fleischer, R. Fröhlich: "Intramolecular Diels-Alder Reaction of Vinylsulfonates Derived from Hydroxyalkyl Substituted 1,3-Dienes and Oxidative Desulfurization of the Resultant Sultones", Tetrahedron 1995, 51, 711-732.

Metz, P., A. Schoop: "Stereoselective [2,3]-Sigmatropic Wittig Rearrangement of Benzyl Ethers Derived from Vinylcuprate Adducts of (R)-2,3-O-Isopropylideneglyceraldehyde", Tetrahedron 1995, 51, 9023-9030.

Lübbers, T., P. Metz: "Formation of C-C Bonds by Allylic Substitution Catalyzed by Palladium Complexes", T. Lübbers, P. Metz in Houben-Weyl, Methods of Organic Chemistry (Eds.: G. Helmchen, R. W. Hoffmann, J. Mulzer, E. Schaumann), Vol. E21c, Thieme, Stuttgart, 1995, p. 2371-2473.

Metz, P.: "Formation of C-N Bonds by Allylic Substitution Catalyzed by Palladium Complexes", P. Metz in Houben-Weyl, Methods of Organic Chemistry (Eds.: G. Helmchen, R. W. Hoffmann, J. Mulzer, E. Schaumann), Vol. E21e, Thieme, Stuttgart, 1995, p. 5643-5669.

Metz, P., U. Meiners, E. Cramer, R. Fröhlich, B. Wibbeling: "A Practical Route to Methyl Nonactate", Chem. Commun. 1996, 431-432.

Metz, P., D. Seng, B. Plietker: "Desulfurization of Sultones with Simultaneous Methylenation", Tetrahedron Lett. 1996, 37, 3841-3844.

Metz, P., B. Hungerhoff: "Enantioselektive Claisen-Umlagerung von Imidsäureestern primärer Allylalkohole" ("Enantioselective Claisen Rearrangement of Imidates Derived from Primary Allyl Alcohols"), GIT Fachz. Lab. 1996, 40, 690-691.

Metz, P., D. Seng, R. Fröhlich, B. Wibbeling: "Intramolecular Diels-Alder Reactions of Vinylsulfonamides", Synlett 1996, 741-742.

Dissertations:

Jörn Stölting: "Totalsynthese des 1,10-seco-Eudesmanolids Ivangulin".

Uta Meiners: "Methodische Untersuchungen zur synthetischen Nutzung von Sultonen - Totalsynthese der Nonactinsäure".

Dieter Seng: " Untersuchungen zur Totalsynthese des molluskiziden Sesquiterpens Ricciocarpin A - Neue Methoden zur Synthese und Nutzung cyclischer Sulfonsäurederivate".

(Funding: Deutsche Forschungsgemeinschaft (4 projects); BASF AG; Ministerium für Wissenschaft und Forschung des Landes Nordrhein-Westfalen; Fonds der Chemischen Industrie.)