2020


P. Löwe, M. Feldt, M. A. Wünsche, L. F. B. Wilm, F. Dielmann
“Oxophosphonium-alkyne cycloaddition reactions: reversible formation of
1,2-oxaphosphetes and six-membered phosphorus heterocycles”
J. Am. Chem. Soc., 2020, 142, 9818-9826.

J. A. Werra, M. A. Wünsche, P. Rathmann, P. Mehlmann, P. Löwe, F. Dielmann
“Effective control of the electron-donating ability of phosphines by using phosphazenyl and phosphoniumylidyl substituents”
Z. anorg. allg. Chem. 2020, 1-7.

W. Uhl, K. Martinewski, J. S. Bruchhage, A. Hepp, M. Layh, F. Dielmann, P.
Mehlmann
“Cooperative activation of azides by an Al/N-based active Lewis pair
unexpected insertion of nitrogen atoms into CSi bonds and formation of
AlCN3 heterocycles”
Z. Naturforsch. 2020, 75b, 63-71.

L. F. B. Wilm, P. Mehlmann, F. Buß, F. Dielmann
“Synthesis and characterization of strongly electron-donating bidentate phosphines containing imidazolin-2-ylidenamino substituents and their electron-rich nickel(0), palladium(II) and gold(I) chelate complexes”
J. Organomet. Chem. 2020, 909, 121097-121104.

M. Abdinejad, C. Dao, B. Deng, M. E. Sweeney, F. Dielmann, X. Zhang, H. B. Kraatz

“Enhanced Electrochemical Reduction of CO2 to CO upon Immobilization onto Carbon Nanotubes Using an Iron‐Porphyrin Dimer”
ChemistrySelect 2020, 5, 979-984.

M. Piesch, F. Dielmann, S. Reichl, M. Scheer
“A general pathway to heterobimetallic triple-decker complexes”
Chem. Eur. J. 2020, ahead of print.

P. Rotering, L. F. B. Wilm, J. A. Werra, F. Dielmann
“Pyridinylidenaminophosphines: facile access to highly electron-rich phosphines”
Chem. Eur. J. 2020, 26, 406-411.


2019


P. Mehlmann, T. Witteler, L. F. B. Wilm, F. Dielmann
“Isolation, characterization and reactivity of three-coordinate phosphorus dications isoelectronic to alanes and silylium cations”
Nat. Chem. 2019, 11, 1139-1143.

S. Cepa, M. Böhmer, F. Roelfes, T. T. Y. Tan, F. Dielmann, F. E. Hahn
“Homo- and Heterodinuclear Head-to-Head or Head-to-Tail Complexes of Rhodium(I) and Iridium(I) with C2,N3 or C8,N9 Bridging Azolato Ligands”
Organometallics 2019, 38, 1982-1990.

L. F. B. Wilm, T. Eder, C. Mück-Lichtenfeld, P. Mehlmann, M. Wünsche, F. Buß, F. Dielmann
"Reversible CO2 fixation by N-heterocyclic imines forming water-stable zwitterionic nitrogen-base-CO2 adducts"
Green Chem. 2019, 21, 640-648.

P. Mehlmann, F. Dielmann
"Switching the Electron-Donating Ability of Phosphines via Proton-Responsive Imidazolin-2-ylidenamino Substituents"
Chem. Eur. J. 2019, 25, 2352-2357. 


2018


T. Witteler, H. Darmandeh, P. Mehlmann, F. Dielmann
"Dialkyl(1,3-diarylimidazolin-2-ylidenamino)phosphines: Strongly electron-donating, Buchwald-type phosphines"
Organometallics 2018, 37 (18), 3064–3072.

F. Buß, P. Rotering, C. Mück-Lichtenfeld, F. Dielmann
"Crystalline, room-temperature stable phosphine-S02 adducts: generation of sulfur monoxide from sulfur dioxide"
Dalton Trans. 2018, 47, 10420-10424.

M. Wünsche, T. Witteler, F. Dielmann
"Lewis Base Free Oxophosphonium Ions: Tunable, Trigonal-planar Lewis Acids"
Angew. Chem. Int. Ed. 2018, 57, 7234-7239.


F. Buß, C. Mück-Lichtenfeld, P. Mehlmann, F. Dielmann
"Nucleopholic Activation of Sulfur Hexafluoride: Metal-free, Selective Degradation by Phosphines"

Angew. Chem. Int. Ed. 2018, 57, 4951-4955; Angew. Chem. 2018, 130, 5045-5049.


2017


C. Ascheberg, J. Bock, F. Buß, C. Mück-Lichtenfeld, C. G. Daniliuc, K. Bergander, F. Dielmann, U. Hennecke "Stable Bromiranium Ions with Weakly-Coordinating Counterions as Efficient Electrophilic Brominating Agents"
Chem. Eur. J. 2017, 23, 11578-11586.

J. J. Chi, T. C. Johnstone, D. Voicu, P. Mehlmann, F. Dielmann, E. Kumacheva, D. W. Stephan
"Quantifying the Efficiency of CO2 Capture by Lewis Pairs"
Chem. Sci. 2017, 8, 3270-3275.

D. Aucamp, T. Witteler, F. Dielmann, S. Siangwata, D. C. Liles, G. S. Smith, D. I. Bezuidenhout
"A tri-arylated 1,2,3-triazol-5-ylidene ligand with a redox-active ferrocenyl substituent for rhodium(I) catalyzed hydroformylation of 1-octene"
Eur. J. Inorg. Chem. 2017, 1227-1236.

F. Dielmann, A. Timoshkin, M. Piesch, G. Balázs, M. Scheer
"The Cobalt cyclo-P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds"
Angew. Chem. Int. Ed
. 2017, 56, 1671-1675;
Angew. Chem. 2017, 129, 1693-1698.

P. Mehlmann, C. Mück-Lichtenfeld, T. T. Y. Tan, F. Dielmann
"Tris(imidazolin-2-ylidenamino)phosphine: A crystalline phosphorus(III) superbase that splits carbon dioxide"
Chem. Eur. J. 2017, 23, 5929-5933.


2016


F. Dielmann, E. V. Peresypkina, B. Krämer, F. Hastreiter, B. P. Johnson, M. Zabel, C. Heindl and M. Scheer
"Cyclo-P4 Building Blocks: Achieving Non-Classical Fullerene Topology and Beyond"
Angew. Chem. Int. Ed. 2016, 55, DOI: 10.1002/anie.201606074.

M. Fleischmann, F. Dielmann, G. Balázs, M. Scheer
"Oxidation Chemistry of Inorganic Benzene Complexes"
Chem. Eur. J. 2016, 22, 15248-15251.

R. A. Khan, F. Dielmann, X. Liu, F. E. Hahn, K. Al-Farhan, A. Alsame, J. Reedijk
"Tetrahedrally Coordinated Luminescent Copper(I) Compounds Containing Halide, Phosphane and Norharmane Ligands"
Polyhedron 2016, 111, 173-178.

F. Buß, P. Mehlmann, C. Mück-Lichtenfeld, K. Bergander, F. Dielmann
"Reversible carbon dioxide binding by simple Lewis base adducts with electron-rich phosphines"
J. Am. Chem. Soc. 2016, 138, 1840–1843.

M. Jaafar, X. Liu, F. Dielmann, F. E. Hahn, K. Al-Farhan, A. Alsame, J. Reedijk
"Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium(chlorido)(cyanido)argentates(I)"
Inorg. Chim. Acta 2016, 443, 45-50.


2015


M. Fleischmann, F. Dielmann, L. J. Gregoriades, E. V. Peresypkina, A. V. Virovets, S. Huber, A. Y. Timoshkin, G. Balázs, M. Scheer
"Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)2(μ,η66-P6)] Towards the "Naked" Cations Cu+, Ag+ and Tl+"
 Angew. Chem. Int. Ed. 2015, 54, 13110-13115; Angew. Chem. 2015, 127, 13303-13308.

M. A. Wünsche, P. Mehlmann, T. Witteler, F. Buß, P. Rathmann, F. Dielmann
"Imidazol-2-ylidenaminophosphines as Highly Electron-rich Ligands for Transition-metal Catalysts"
Angew. Chem. 2015, 127, 12024-12027; Angew. Chem. Int. Ed. 2015, 54, 11857-11860.

F. Dielmann, G. Bertrand
"Reactivity of a Stable Phosphinonitrene towards Small Molecules"
Chem. Eur. J. 2015, 21, 191-198.

A. Alsalme, M. Jaafar, X Liu, F. Dielmann, F. E. Hahn, K. Al-farhan, J. Reedijk
"Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium (phenylacetylido)(cyanido)aurate(I) monoacetone monohydrate, (PPN)[Au(CN)(CCC6H5)] H2O (CH3)2CO and bis(triphenylphosphane)iminium (t-butylacetylido)(cyanido)aurate(I) monohydrate, (PPN)[Au(CN)(CCC4H9)] H2O"
Polyhedron 2015, 88, 1-5.


2014


F. Dielmann, D. M. Andrada, G. Frenking, G. Bertrand
"Isolation of Bridging and Terminal Coinage Metal-Nitrene Complexes"
J. Am. Chem. Soc. 2014, 136, 3800-3802.


2013


T. Li, N. Arleth, M. T. Gamer, R. Köppe, T. Augenstein, F. Dielmann, M. Scheer, S. N. Konchenko, P. W. Roesky
"Intramolecular Phosphorus-Phosphorus Bond Formation within a Co2P4 Core"
Inorg. Chem. 2013, 52, 14231-14236.

F. Dielmann, C. E. Moore, A. L. Rheingold, G. Bertrand
"Crystalline, Lewis Base-Free, Cationic Phosphoranimines (Iminophosphonium Salts)"
J. Am. Chem. Soc. 2013, 135, 14071-14073.


2012


F. Dielmann, O. Back, M. Henry-Ellinger, P. Jerabek, G. Frenking, G. Bertrand
"A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom-Transfer Agent"
Science
2012, 337, 1526.

F. Dielmann, A. Schindler, S. Scheuermayer, J. Bai, R. Merkle, M. Zabel, A. V. Virovets, E. V. Peresypkina, G. Brunklaus, H. Eckert, M. Scheer
"Coordination Polymers Based on [Cp*Fe(η5-P5)]: Solid-State Structure and MAS NMR Studies"
Chem. Eur. J. 2012, 18, 1168-1179.


2011


F. Dielmann (Dissertation)
"Novel phosphorus ligand complexes and their use in supramolecular chemistry"
München: Verlag Dr. Hut, 2011 [ISBN 9783868538946].


2010


F. Dielmann, M. Sierka, A. V. Virovets, M. Scheer
"Access to Extended Polyphosporus Frameworks"
 Angew. Chem. 2010, 122, 7012-7016; Angew. Chem. Int. Ed. 2010, 49, 6860-6864

F. Dielmann, R. Merkle, S. Heinl, M. Scheer
"Synthesis and reactivity of low-valent group 14 element compounds"
Z. Anorg. Allg. Chem. 2010, 636, 1275-1285.


2009


F. Dielmann, R. Merkle, S. Heinl, M. Scheer
"New pentaphosphaferrocenes"
Z. Naturforsch. 2009, 64b, 3-10.


2008


M. H. Chisholm, A. S. Dann, F. Dielmann, J. C. Gallucci, N. J. Patmore, R. Ramnauth, M. Scheer
"Dimolybdenum Bis-2,4,6-triisopropyl-benzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4'-Bipyridine with Ambivalent Properties"
Inorg. Chem. 2008, 47, 9248-9255.

M. Scheer, L. J. Gregoriades, R. Merkle, B. P. Johnson, F. Dielmann
"Dynamic Investigation on Supramolecular Compounds using Pn ligand complexes"
Phosphorus, Sulfur and Silicon and the Related Elements 2008, 183, 504-508.


2006


B. P. Johnson, F. Dielmann, G. Balázs, M. Sierka, M. Scheer
"Spherical Cluster Comprising a Four- and Six-Membered-Ring Motif"
Angew. Chem. 2006, 118, 2533-2536; Angew. Chem. Int. Ed. 2006, 45, 2473-2475.